1-Bromo-2-(bromomethyl)-4-iodobenzene

Base Information

Chemical Name:1-Bromo-2-(bromomethyl)-4-iodobenzene
CAS No.:289617-98-7
Molecular Formula:C7H5Br2I
Molecular Weight:375.829
Hs Code.:2903999090
DSSTox Substance ID:DTXSID70697087
Nikkaji Number:J2.150.806C
Wikidata:Q82626908
Mol file:289617-98-7.mol

Synonyms:289617-98-7;1-BROMO-2-(BROMOMETHYL)-4-IODOBENZENE;2-Bromo-5-iodobenzyl bromide;2-BROMO-5-IODOBENZYLBROMIDE;Benzene, 1-bromo-2-(bromomethyl)-4-iodo-;SCHEMBL15271148;DTXSID70697087;ZUXVQLWVDZQCMV-UHFFFAOYSA-N;CL9154;MFCD15527653;AS-46227;CS-0450634;EN300-2978031

Suppliers and Price of 1-Bromo-2-(bromomethyl)-4-iodobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
2-Bromo-5-iodobenzyl bromide
250 mg
$ 128.00

SynQuest Laboratories
2-Bromo-5-iodobenzyl bromide
1 g
$ 320.00

SynQuest Laboratories
2-Bromo-5-iodobenzyl bromide
5 g
$ 960.00

Crysdot
1-Bromo-2-(bromomethyl)-4-iodobenzene 97%
5g
$ 1682.00

Crysdot
1-Bromo-2-(bromomethyl)-4-iodobenzene 97%
1g
$ 559.00

Apolloscientific
2-Bromo-5-iodobenzylbromide
1g
$ 227.00

Apolloscientific
2-Bromo-5-iodobenzylbromide
250mg
$ 102.00

Apolloscientific
2-Bromo-5-iodobenzylbromide
5g
$ 870.00

Alichem
2-Bromo-5-iodobenzylbromide
1g
$ 1445.30

Alichem
2-Bromo-5-iodobenzylbromide
500mg
$ 806.85

Total 4 raw suppliers

Chemical Property of 1-Bromo-2-(bromomethyl)-4-iodobenzene

Chemical Property:

PSA：0.00000
LogP:3.94860
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:375.77822
Heavy Atom Count:10
Complexity:108

Purity/Quality:

98% ^*data from raw suppliers

2-Bromo-5-iodobenzyl bromide ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C=C1I)CBr)Br

Technology Process of 1-Bromo-2-(bromomethyl)-4-iodobenzene

There total 4 articles about 1-Bromo-2-(bromomethyl)-4-iodobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 202865-85-8
1-bromo-4-iodo-2-methylbenzene

: 289617-98-7
2?bromo-4?iodobromomethylbenzene

Guidance literature:: With N-Bromosuccinimide; dibenzoyl peroxide; In benzene; for 6h; Irradiation;
DOI:10.1016/j.bmc.2008.05.062

Reference yield:

: 6933-10-4
amino-5-bromo-2-toluene

: 289617-98-7
2?bromo-4?iodobromomethylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: aq. HCl / 1.5 h / 90 - 95 °C

1.2: aq. NaNO₂ / 0.5 h / 0 °C

1.3: 74 percent / aq. KI / 20 °C

2.1: 62 percent / N-bromosuccinimide; benzoyl peroxide / 24 h / 80 °C

With hydrogenchloride; N-Bromosuccinimide; dibenzoyl peroxide;
DOI:10.1021/ja0009119

Reference yield:

: 95-53-4
o-toluidine

: 289617-98-7
2?bromo-4?iodobromomethylbenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydrogencarbonate; tetrabutylammomium bromide; iodine / water / 10 - 15 °C

2.1: sodium nitrite; sulfuric acid / 1 h / 10 - 15 °C

2.2: 1 h / 85 - 90 °C

3.1: 2,2'-azobis(isobutyronitrile); N-Bromosuccinimide / dichloromethane / 10 h / 50 - 60 °C

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); sulfuric acid; tetrabutylammomium bromide; iodine; sodium hydrogencarbonate; sodium nitrite; In dichloromethane; water;