Phenylethylidenehydrazine

Base Information

• Chemical Name: Phenylethylidenehydrazine
• CAS No.: 29443-41-2
• Molecular Formula: C8H10N2
• Molecular Weight: 134.181
• UNII: 9FZ4W7J6VE
• Wikipedia: Phenylethylidenehydrazine
• ChEMBL ID: CHEMBL2235132
• Mol file: 29443-41-2.mol

Synonyms:PEH cpd;phenylethylidenehydrazine

Chemical Property of Phenylethylidenehydrazine

Chemical Property:

• PSA: 38.38000
• LogP: 1.87390
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 134.084398327
• Heavy Atom Count: 10
• Complexity: 104

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CC=NN
• Isomeric SMILES: C1=CC=C(C=C1)C/C=N/N

Technology Process of Phenylethylidenehydrazine

There total 4 articles about Phenylethylidenehydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenylacetaldehyde (122-78-1) → β-phenylethylidenehydrazine (29443-41-2)

Guidance literature:

With hydrazine hydrate; In dimethyl sulfoxide;

DOI:10.1039/b303221c

Reference yield:

→ β-phenylethylidenehydrazine (29443-41-2)

Guidance literature:

Phenylacetaldehyd, N2H4 (S. 2374);

Reference yield:

→ 5α,9α-Lumistadien-7,22-on-3 (1431-87-4,3464-55-9,27241-06-1,32507-77-0,97168-85-9,121786-15-0)

Guidance literature:

5α,9α-Lumistadien-7,22-ol-3β, Acn., wss. Chromsaeure (8N), 20grad;

upstream raw materials:

5α,9α-Lumistadien-7,22-on-3

phenylacetaldehyde

Downstream raw materials:

1,1-diiodo-2-phenylethane

1,1,3,-triphenyl-1-propene

(Z)-1,3-diphenyl-2-butene

(E)-β-benzyl-α-methylstyrene

Refernces

• 1、 Kan, Jian,Li, Chao-Jun,Li, Chen-Chen,Li, Jianbin,Lv, Leiyang,Qiu, Zihang. "Synergistic Relay Reactions To Achieve Redox-Neutral α-Alkylations of Olefinic Alcohols with Ruthenium(II) Catalysis". supporting information. p. 4544 - 4549. Retrieved 2020/02/04.
• 2、 Cao, Dawei,Chen, Zhangpei,Li, Chao-Jun,Lv, Leiyang,Yao, Jinzhong,Yu, Lin. "Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones". . p. 10759 - 10763. Retrieved 2020/10/26.