trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

Base Information

Chemical Name:trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]
CAS No.:1312816-12-8
Molecular Formula:C₃₆H₂₀F₈I₂P₂Pd₂
Molecular Weight:1133.14
Hs Code.:

Synonyms:

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Chemical Property of trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

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Technology Process of trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

There total 2 articles about trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1312816-05-9,919536-99-5
[Pd2(μ-acetato)2(κ2-2-C6F4PPh2)2]

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 1312816-12-8
cis-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

: 1312816-12-8
trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

Guidance literature:: In methanol; dichloromethane; under Ar; soln. of Pd complex in CH2Cl2 treated with soln. of NaI in MeOH; stirred for 15 min; solvent evapd. under reduced pressure; extd. with CH2Cl2; filtered through Celite; filtrate evapd. to dryness; mixt. of trans and cis isomers (2:1) obtained, total yield 80%; elem. anal.;
DOI:10.1021/om200179v

Reference yield:

: 1312816-05-9,919536-99-5
[Pd2(μ-acetato)2(κ2-2-C6F4PPh2)2]

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 1312816-12-8
cis-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

: 1312816-12-8
trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

Guidance literature:: In methanol; dichloromethane; under Ar; soln. of Pd complex in CH2Cl2 treated with soln. of NaI in MeOH; stirred for 15 min; solvent evapd. under reduced pressure; extd. with CH2Cl2; filtered through Celite; filtrate evapd. to dryness; mixt. of trans and cis isomers (2:1) obtained, total yield 80%; elem. anal.;
DOI:10.1021/om200179v

Reference yield:

: 1312816-12-8
cis-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

: 1312816-12-8
trans-[Pd2(μ-I)2(κ2-2-C6F4PPh2)2]

: [Pd4(μ-I)4(μ-2-C6F4PPh2)4]*1.68CH2Cl2

: [(κ2-2-C6F4PPh2)Pd(μ-I)(μ-2-C6F4PPh2)Pd(μ-I)2Pd(μ-I)(μ-2-C6F4PPh2)Pd(κ2-2-C6F4PPh2)]*2CH2Cl2

Guidance literature:: In not given; under Ar; soln. of Pd complex set aside over several d; not isolated; inseparable mixt. of two Pd4 complexes obtained; detd. by (31)P NMR spectra;
DOI:10.1021/om200179v