RhS₂COCH₃(P(C₆H₄CH₃)3)2

Base Information

Chemical Name:RhS₂COCH₃(P(C₆H₄CH₃)3)2
CAS No.:112388-60-0
Molecular Formula:C₄₄H₄₅OP₂RhS₂
Molecular Weight:818.826
Hs Code.:

RhS<sub>2</sub>COCH<sub>3</sub>(P(C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)3)2

Synonyms:

Suppliers and Price of RhS₂COCH₃(P(C₆H₄CH₃)3)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of RhS₂COCH₃(P(C₆H₄CH₃)3)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of RhS₂COCH₃(P(C₆H₄CH₃)3)2

There total 2 articles about RhS₂COCH₃(P(C₆H₄CH₃)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112388-54-2
Rh(CO)2S₂COCH₃

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 112388-60-0
RhS₂COCH₃(P(C₆H₄CH₃)3)2

Guidance literature:: In acetone; Irradiation (UV/VIS); (N2); to soln. of Rh complex was added excess of the phosphine and irradiated with UV light for 9 h; soln. was concd., addn. of Et2O and then hexane gave ppt. which was filtered off and dried over P2O5; elem. anal.;
DOI:10.1016/0022-328X(87)85138-0

Reference yield:

: {RhCl(bicyclo{2.2.2}octa-2,5-diene)}2

: 2667-20-1
potassium methylxanthate

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 112388-60-0
RhS₂COCH₃(P(C₆H₄CH₃)3)2

Guidance literature:: In toluene; (N2); to suspn. of KS2COMe was added Rh complex (2:1 mol), filtered soln. was treated with phosphine ligand and stirred for 30 min; solvent was partially removed and product crystd. by addn. of Et2O and hexane;
DOI:10.1016/0022-328X(87)85138-0