Mercury, bis(propylthiolato)-

Base Information

• Chemical Name: Mercury, bis(propylthiolato)-
• CAS No.: 4080-28-8
• Molecular Formula: C6H14HgS2
• Molecular Weight: 350.8954
• DSSTox Substance ID: DTXSID90193793
• Nikkaji Number: J1.498.304J
• Mol file: 4080-28-8.mol

Synonyms:Mercury, bis(propylthiolato)-;4080-28-8;1-Propanethiol, mercury(2+) salt;Bis(propylthio) mercury(II);C3H8S.1/2Hg;C3-H8-S.1/2Hg;DTXSID90193793;1-Propanethiol, mercury(2) salt

Chemical Property of Mercury, bis(propylthiolato)-

Chemical Property:

• Vapor Pressure: 156mmHg at 25°C
• Boiling Point: 67.8°C at 760 mmHg
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 352.024336
• Heavy Atom Count: 9
• Complexity: 7.2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[S-].CCC[S-].[Hg+2]

Technology Process of Mercury, bis(propylthiolato)-

There total 6 articles about Mercury, bis(propylthiolato)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.4%

1-thiopropane (107-03-9) + mercury(II) nitrate → bis(n-propanethiolato)mercury(II) (4080-28-8)

Guidance literature:

In ethanol; water; the thiol was added to soln. of Hg(NO3)2 in EtOH/H2O in a Schlenk tube; soln. was stirred for 12 h in the dark; ppt. was filtered off, washed with cold EtOH and dried in vacuo;

DOI:10.1021/ic000638b

Reference yield: 88.0%

1-thiopropane (107-03-9) + mercury(II) cyanide → bis(n-propanethiolato)mercury(II) (4080-28-8)

Guidance literature:

In methanol; inert atm.; molar ratio Hg(CN)2:RSH 1:2.2, stirring, shaking (10 h); filtn., washing (MeOH), recrystn. or extraction (MeOH, protection against light), drying (over KOH, 1E-3 to 1E-5 mbar, 1-2 weeks);

DOI:10.1002/(SICI)1521-3749(199912)625:12<2085::AID-ZAAC2085>3.3.CO;2-J

Reference yield: 77.2%

1-thiopropane (107-03-9) + mercury(II) iodide → bis(n-propanethiolato)mercury(II) (4080-28-8)

Guidance literature:

With triethylamine; In ethanol; byproducts: triethylammonium iodide; the thiol was added to soln. of HgI2 in EtOH in a Schlenk tube; Et3N wasadded; ppt. was filtered off, washed with water and dried in vacuo;

DOI:10.1021/ic000638b

upstream raw materials:

bis(n-octanethiolato)mercury(II)

Dipropyl disulfide

1-thiopropane

bis(n-heptanethiolato)mercury(II)

Refernces

• 1、 Grobe,Vetter. "Perfluoromethyl element ligands. XLI. [1] compounds of the type (F3C)2EE′R with pseudohalide character (E = P, As; E′ = S, Se, Te)". . p. 2085 - 2094. Retrieved 2008/10/08.