(Pentafluoroethyl)benzene

Base Information

• Chemical Name: (Pentafluoroethyl)benzene
• CAS No.: 309-11-5
• Molecular Formula: C8H5F5
• Molecular Weight: 196.12
• Hs Code.: 2903999090
• Mol file: 309-11-5.mol

Synonyms:pentafluoroethyl-benzene;Pentafluoraethyl-benzol;trifluoromethylbenzal fluoride;

Chemical Property of (Pentafluoroethyl)benzene

Chemical Property:

• Boiling Point: 128-129 °C(Press: 733 Torr)
• PSA: 0.00000
• Density: 1.304±0.06 g/cm3(Predicted)
• LogP: 3.34070

Purity/Quality:

98%min ^*data from raw suppliers

(Pentafluoroethyl)benzene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Pentafluoroethyl)benzene

There total 34 articles about (Pentafluoroethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

iodobenzene (591-50-4) + pentafluoroethylcopper(I) (60007-39-8) → (pentafluoroethyl)benzene (309-11-5)

Guidance literature:

at 50 ℃; for 24h;

Reference yield: 95.0%

bromobenzene (108-86-1,52753-63-6) + pentafluoroethylcopper(I) (60007-39-8) → (pentafluoroethyl)benzene (309-11-5)

Guidance literature:

at 80 ℃; for 72h;

Reference yield: 85.0%

iodobenzene (591-50-4) + (1,1,2,2,2-pentafluoroethyl)(1,10-phenanthroline-κΝ1,κN10)-copper → (pentafluoroethyl)benzene (309-11-5)

Guidance literature:

In d₇-N,N-dimethylformamide; N,N-dimethyl-formamide; at 60 ℃; for 5h; Inert atmosphere;

DOI:10.1002/chem.201802415

upstream raw materials:

(2,2,2-trichloro-1,1-difluoro-ethyl)-benzene

2,2,2-Trifluoroacetophenone

bromobenzene

iodotrifluoromethane

Downstream raw materials:

N,N-dimethyl-3-(pentafluoroethyl)aniline

3-(perfluoroethyl)aniline

4-amino-6-pentafluoroethyl-benzene-1,3-disulfonic acid diamide

3-Amino-1-pentafluorethyl-benzol-sulfonsaeure-⁽⁴⁾

Refernces

• 1、 Baya, Miguel,Joven-Sancho, Daniel,Alonso, Pablo J.,Orduna, Jesús,Menjón, Babil. "M?C Bond Homolysis in Coinage-Metal [M(CF3)4]? Derivatives". supporting information. p. 9954 - 9958. Retrieved 2019/06/24.
• 2、 Ohashi, Masato,Ishida, Naoyoshi,Ando, Kota,Hashimoto, Yu,Shigaki, Anna,Kikushima, Kotaro,Ogoshi, Sensuke. "CuI-Catalyzed Pentafluoroethylation of Aryl Iodides in the Presence of Tetrafluoroethylene and Cesium Fluoride: Determining the Route to the Key Pentafluoroethyl CuI Intermediate". supporting information. p. 9794 - 9798. Retrieved 2018/07/25.