Quinoline, 1,4-dihydro-1-methyl-

Base Information

• Chemical Name: Quinoline, 1,4-dihydro-1-methyl-
• CAS No.: 30958-75-9
• Molecular Formula: C10H11N
• Mol file: 30958-75-9.mol

Synonyms:

Chemical Property of Quinoline, 1,4-dihydro-1-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Quinoline, 1,4-dihydro-1-methyl-

There total 2 articles about Quinoline, 1,4-dihydro-1-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-methylquinolinium perchlorate → 1-Methyl-1,2-dihydroquinoline (16021-60-6) + 1-methyl-1,4-dihydroquinoleine (30958-75-9)

Guidance literature:

With tetrabutyl ammonium fluoride; HSiPh₃; In [D₃]acetonitrile; at 24.85 ℃; for 100h; Further Variations:; Reagents; Times; Product distribution;

DOI:10.1021/jp003518y

Reference yield:

1-methylquinolinium cation (21979-19-1) → 1-Methyl-1,2-dihydroquinoline (16021-60-6) + 1-methyl-1,4-dihydroquinoleine (30958-75-9)

Guidance literature:

With tri-n-butyl-tin hydride; In acetonitrile; at 24.9 ℃; Product distribution; Mechanism; Quantum yield; other quinolinium ion; other reagent; irradiation, deuterium kinetic isotope effect;

DOI:10.1039/c39940000287

Reference yield: 90.0%

1-methyl-1,4-dihydroquinoleine (30958-75-9) + phenyl isocyanate (103-71-9) → (2aR*8aR*) 8-methyl-1-phenyl-2a,3,8,8a-tetrahydroazeto <2,3-b> quinolein-2(1H)-one (136463-57-5,147815-92-7)

Guidance literature:

for 24h; Ambient temperature;

upstream raw materials:

1-methylquinolinium cation

Downstream raw materials:

(2aR^*8aR^*) 8-methyl-1-phenyl-2a,3,8,8a-tetrahydroazeto <2,3-b> quinolein-2(1H)-one

N-phenyl-1-methyl-1,4-dihydroquinoleine-3-carboxamide