trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]

Base Information

Chemical Name:trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]
CAS No.:75247-42-6
Molecular Formula:C₂₂H₂₅Cl₂PPtS
Molecular Weight:618.466
Hs Code.:

trans-[Pt(PPh<sub>3</sub>)(diethyl sulphide)Cl<sub>2</sub>]

Synonyms:

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Chemical Property of trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]

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Technology Process of trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]

There total 3 articles about trans-[Pt(PPh₃)(diethyl sulphide)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: {PtCl₂(PPh₃)}2

: 352-93-2
diethyl sulphide

: 75247-42-6
trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]

Guidance literature:: In acetone; treatment of Pt-complex suspn. with org. ligand (5% excess) (0°C,vigorous stirring, 3-4 h), according to: J. Chatt, L. M. Venenzi, J. Ch em. Soc. 3858 (1955); ppt. filtration off, washing (cold acetone), drying, vac. desiccator, room temp.); elem. anal.; thermogravimetric and differential thermal anal.;

Reference yield:

: 84835-92-7
Pt(P(C₆H₅)3)Cl₃^(1-)*N(C₂H₅)4⁽¹⁺⁾={Pt(P(C₆H₅)3)Cl₃}N(C₂H₅)4

: 352-93-2
diethyl sulphide

: 75247-42-6
trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]

Guidance literature:: In methanol; water; byproducts: Cl(1-); 95% MeOH, 5% H2O; 25.0°C;; not isolated, identified spectrophotometrically;; Kinetics;
DOI:10.1039/DT9880002347

Reference yield:

: {PtCl₂(PPh₃)}2

: 70-29-1
diethyl sulphide

: 75247-42-6
trans-[Pt(PPh₃)(diethyl sulphide)Cl₂]

Guidance literature:: In acetone; 5% excess of sulphide, 0°C, stirring for 3-4 h; collection (filtration), washing (cold Me2CO), drying (vac. desiccator, room temp.); elem. anal.;