Carbamic acid, bis(1-methylethyl)-, methyl ester

Base Information

• Chemical Name: Carbamic acid, bis(1-methylethyl)-, methyl ester
• CAS No.: 31603-49-3
• Molecular Formula: C8H17NO2
• Molecular Weight: 159.228
• Hs Code.: 2924199090
• Mol file: 31603-49-3.mol

Synonyms:diisopropyl-carbamic acid methyl ester;methyl N,N-diisopropylcarbamate;N'-Carbomethoxydiisopropylamine;N-methoxycarbonyl-N,N-diisopropylamine;Methyl diisopropylcarbamate;Diisopropyl-carbamidsaeure-methylester;

Chemical Property of Carbamic acid, bis(1-methylethyl)-, methyl ester

Chemical Property:

• PSA: 29.54000
• LogP: 1.87160

Purity/Quality:

Methyldiisopropylcarbamate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamic acid, bis(1-methylethyl)-, methyl ester

There total 3 articles about Carbamic acid, bis(1-methylethyl)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

N-carbomethoxy-N,N'-dimethyl-2-oxoimidazolinium fluoroborate + diisopropylamine (108-18-9) → 1,3-dimethyl-2-imidazolidinone (80-73-9) + N-methoxycarbonyl-N,N-diisopropylamine (31603-49-3) + N,N-diisopropylammonium tetrafluoroborate

Guidance literature:

In nitromethane; Product distribution; Ambient temperature;

DOI:10.1021/ja00531a041

Reference yield:

1-bromo-3-chlorobenzene (108-37-2) + diisopropylamine (108-18-9) + methyl chloroformate (79-22-1) → N-methoxycarbonyl-N,N-diisopropylamine (31603-49-3) + methyl 2-acetyl-6-chlorobenzoate (685892-23-3)

Guidance literature:

1-bromo-3-chlorobenzene; diisopropylamine; With n-butyllithium; In tetrahydrofuran; hexane; for 3h;

methyl chloroformate; In tetrahydrofuran; at -78 ℃; for 1.25h;

DOI:10.1021/op0501444

Reference yield:

diisopropylamine (108-18-9) + methyl chloroformate (79-22-1) → N-methoxycarbonyl-N,N-diisopropylamine (31603-49-3)

Guidance literature:

upstream raw materials:

diisopropylamine

methyl chloroformate

1-bromo-3-chlorobenzene

Downstream raw materials:

N,N-diisopropylmethylamine

(1-hydroxycyclohexyl)methyl N,N-diisopropylcarbamate

1-cyclohexenylmethyl N,N-diisopropylcarbamate