{Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF₆)2

Base Information

• Chemical Name: {Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF₆)2
• CAS No.: 119679-84-4
• Molecular Formula: C₄₆H₄₀N₄P₂Ru*2F₆P
• Molecular Weight: 1101.8
• Mol file: 119679-84-4.mol

Synonyms:

Chemical Property of {Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF₆)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF₆)2

There total 2 articles about {Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF₆)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Ru(bpy)2Cl2}*3H2O + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → {Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF6)2 (119679-84-4)

Guidance literature:

In ethanol; water; EtOH/H2O soln. of (Ru(bipy)2Cl2)*3H2O and 1,2-bis(diphenylphosphino)ethane was purged with N2 and refluxing for 2 weeks, KPF6 was added to form a yellow precipitate; recrystallisation from H2O/isopropanol;

DOI:10.1021/j100347a015

Reference yield:

potassium hexafluorophosphate (17084-13-8) + {Ru(bpy)2Cl2}*3H2O + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → {Ru(2,2'-bipyridine)2(1,2-bis(diphenylphosphino)ethane)}(PF6)2 (119679-84-4)

Guidance literature:

In ethanol; water; keep under N2; reflux a soln. of Ru-compd. and dppe in water/ethanol (1:1) for 6 h; reflux continued for 2 weeks; filtration; addn. of KPF6; pptn.; filtration of ppt. from the hot soln.; cooling filtrate to room temp.; pptn.; collection of ppt.; initial collection from the hot soln. was product with some unknown impurity; second collection was pure;

DOI:10.1021/j100357a018

upstream raw materials:

potassium hexafluorophosphate

1,2-bis-(diphenylphosphino)ethane