[Rh((R,R)-t-Bu-BisP*)(H2-η6-methyl acetylaminocinnamate)]BF4

Base Information

• Chemical Name: [Rh((R,R)-t-Bu-BisP*)(H2-η6-methyl acetylaminocinnamate)]BF4
• CAS No.: 290350-07-1
• Molecular Formula: BF₄*C₂₄H₄₃NO₃P₂Rh
• Molecular Weight: 645.268
• Mol file: 290350-07-1.mol

Synonyms:

Chemical Property of [Rh((R,R)-t-Bu-BisP*)(H2-η6-methyl acetylaminocinnamate)]BF4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh((R,R)-t-Bu-BisP*)(H2-η6-methyl acetylaminocinnamate)]BF4

There total 1 articles about [Rh((R,R)-t-Bu-BisP*)(H2-η6-methyl acetylaminocinnamate)]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

d(4)-methanol (811-98-3) + [(Rh((R,R)-t-Bu-BisP*)H)3(μ2-H)3(μ3-H)][BF4]2 + N-acetyl dehydrophenylalanine methyl ester (52386-78-4) → [Rh((S,S)-1,2-bis(tert-butylmethylphosphino)ethane)(CD3OD)2]BF4 (290349-97-2) + [Rh((R,R)-t-Bu-BisP*)(H2-η6-methyl acetylaminocinnamate)]BF4 (290350-07-1) + [Rh((R,R)-t-Bu-BisP*)(methyl acetylaminocinnamate)]BF4 (290356-61-5)

Guidance literature:

In d⁽⁴⁾-methanol; under Ar; in NMR tube; Rh complex and ligand (1.3-fold excess) dissolvedin MeOH-d4; sealed; reacted for 25 d; not isolated; monitored by (31)P NMR spectra;

DOI:10.1039/c0dt01564d

upstream raw materials:

d⁽⁴⁾-methanol

N-acetyl dehydrophenylalanine methyl ester