[Mo2(η5-cyclopentadienyl)(η5-C5H4CH2Ph)(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2]

Base Information

• Chemical Name: [Mo2(η5-cyclopentadienyl)(η5-C5H4CH2Ph)(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2]
• CAS No.: 1224571-68-9
• Molecular Formula: C₃₅H₄₈Mo₂O₄P₂
• Molecular Weight: 786.591
• Mol file: 1224571-68-9.mol

Synonyms:

Chemical Property of [Mo2(η5-cyclopentadienyl)(η5-C5H4CH2Ph)(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo2(η5-cyclopentadienyl)(η5-C5H4CH2Ph)(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2]

There total 1 articles about [Mo2(η5-cyclopentadienyl)(η5-C5H4CH2Ph)(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

diphosphorous acid tetraethyl ester (21646-99-1) + [(η5-cyclopentadienyl)2Mo2(μ-carbonyl)(μ-methoxycarbyne)(μ-dicyclohexylphosphide)] + toluene (108-88-3,15644-74-3,16713-13-6) → [Mo2(η5-cyclopentadienyl)2(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2] (537683-58-2) + [Mo2(η5-cyclopentadienyl)(η5-C5H4CH2Ph)(μ-dicyclohexylphosphide)(μ-diethoxyphosphide)(CO)2] (1224571-68-9)

Guidance literature:

In toluene; placing of toluene soln. of Mo2Cp2(μ-COMe)(μ-PCy2)(μ-CO) and (EtO)2POP(OEt)2 into Schlenk tube, heating at 363 K for 24 h; removal of solvent under vac., extn. with CH2Cl2-petroleum ether (1:5), chromy. on alumina (activity II) at 243 K; elution with CH2Cll2-petroleum ether (1:4), removal of solvents from first and second fraction;

DOI:10.1021/om100117a

upstream raw materials:

diphosphorous acid tetraethyl ester

toluene

Refernces