methyl(phenyl)carbamodithioic acid

Base Information

• Chemical Name: methyl(phenyl)carbamodithioic acid
• CAS No.: 42139-51-5
• Molecular Formula: C8H12N2S2
• Molecular Weight: 200.329
• Mol file: 42139-51-5.mol

Synonyms:Carbanilicacid, N-methyldithio-, NH4 salt (7CI);

Chemical Property of methyl(phenyl)carbamodithioic acid

Chemical Property:

• Vapor Pressure: 0.0195mmHg at 25°C
• Refractive Index: 1.686
• Boiling Point: 252.3°C at 760 mmHg
• Flash Point: 106.4°C
• Density: 1.251g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl(phenyl)carbamodithioic acid

There total 3 articles about methyl(phenyl)carbamodithioic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

carbon disulfide (75-15-0,12122-00-8) + N-methylaniline (100-61-8) → ammonium N-methyl-N-phenyldithiocarbamate (42139-51-5)

Guidance literature:

With ammonia; In water; Cooling with ice;

DOI:10.1080/00958972.2011.606906

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + benzhydrylidene(methyl)amine (552-82-9) → ammonium N-methyl-N-phenyldithiocarbamate (42139-51-5)

Guidance literature:

benzhydrylidene(methyl)amine; With ammonia; for 0.0833333h; Cooling with ice;

carbon disulfide; Cooling with ice;

DOI:10.1016/j.ica.2016.03.033

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + N-methylaniline (100-61-8) → ammonium N-methyl-N-phenyldithiocarbamate (42139-51-5)

Guidance literature:

With water;

upstream raw materials:

carbon disulfide

N-methylaniline

benzhydrylidene(methyl)amine

Downstream raw materials:

O-<4-Chlor-phenyl>-S--dithiocarbonat

α-(nitromethyl)benzyl N-methyldithiocarbanilate

O-(4-chlorophenyl) N-methyl-N-phenyl thiocarbamate

Refernces

• 1、 Adeyemi, Jerry O.,Onwudiwe, Damian C.,Ekennia, Anthony C.,Uwaoma, Romanus C.,Hosten, Eric C.. "Synthesis, characterization and antimicrobial studies of organotin(IV) complexes of N-methyl-N-phenyldithiocarbamate". . p. 148 - 159. Retrieved 2018.