DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM

Base Information

Chemical Name:DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM
CAS No.:12375-04-1
Molecular Formula:C₁₂H₄O₁₂Os₄
Molecular Weight:1100.96
Hs Code.:
Mol file:12375-04-1.mol

Synonyms:Osmium,dodecacarbonyltetrahydrotetra- (8CI); Dodecacarbonyltetra-m-hydridotetraosmium;Dodecacarbonyltetra-m-hydrotetraosmium; Dodecacarbonyltetrahydridotetraosmium;Dodecacarbonyltetrahydrotetraosmium

Suppliers and Price of DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM 95.00%
5MG
$ 495.77

Total 9 raw suppliers

Chemical Property of DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM

Chemical Property:

PSA：0.00000
LogP:-0.50520

Purity/Quality:

99% ^*data from raw suppliers

DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM

There total 3 articles about DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

: Os3(CO)10(μ-H)2

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 12375-04-1
Os4(μ-H)4(CO)12

: 80800-50-6
Os3(μ-H,μ-OCN(CH3)2)(CO)10

Guidance literature:: In nonane; N,N-dimethyl-formamide; under N2: addn. of 0.26 mmol N,N-dimethyl formamide to a soln. of 0.2 mmol Os3(μ-H)2(CO)10 in nonane; stirring at room temperature overnight; heating to 150°C for 3 h; removing of nonane and excess formamide under reduced pressure;; chromy. (silica gel, 10% hexane/CH2Cl2): three band: Os3(μ-H)2(CO)10, Os3(H,OCN(CH3)2)(CO)10, Os4(μ-H)4(CO)12;;
DOI:10.1016/0022-328X(84)80467-2

Reference yield:

: 97689-39-9
HOs₃(CH₃OCCC₆H₅CC₆H₅)(CO)9

: 12375-04-1
H₄Os₄(CO)12

Guidance literature:: With hydrogen; In not given;
DOI:10.1021/om00129a004

Reference yield:

: 76287-22-4
HOs₃(HOCCHCH)(CO)9

: 12375-04-1
H₄Os₄(CO)12

Guidance literature:: With hydrogen; In octane; cyclohexane; High Pressure; a soln. of the cluster was pressurized with 2 atm of H2 and heated at 80°C for 24 h, then evapd. to dryness, dissolved in octane, heatedat 123°C for 6 d; identified by IR spectrum;
DOI:10.1021/om00129a004