sodium 2,6-dichlorophenolate

Base Information

• Chemical Name: sodium 2,6-dichlorophenolate
• CAS No.: 29726-01-0
• Molecular Formula: C6H4 Cl2 O . Na
• Molecular Weight: 184.985
• Hs Code.: 2908199090
• Mol file: 29726-01-0.mol

Synonyms:Phenol,2,6-dichloro-, sodium salt (8CI,9CI); Sodium 2,6-dichlorophenolate; Sodium2,6-dichlorophenoxide

Chemical Property of sodium 2,6-dichlorophenolate

Chemical Property:

• Vapor Pressure: 0.0828mmHg at 25°C
• Boiling Point: 219°C at 760 mmHg
• Flash Point: 94.9°C
• PSA: 23.06000
• LogP: 3.13720

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium 2,6-dichlorophenolate

There total 1 articles about sodium 2,6-dichlorophenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2,6-Dichlorophenol (87-65-0) → sodium 2,6-dichlorophenolate (29726-01-0)

Guidance literature:

With sodium hydroxide; In methanol; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201405060

Reference yield: 96.0%

iron(II) trifluoromethanesulfonate acetonitrile disolvate + cis,cis-1,3,5-tris-(E)-(o-tolylideneimino)cyclohexane (1257225-98-1) + sodium 2,6-dichlorophenolate (29726-01-0) → [Fe(cis,cis-1,3,5-tris-(E)-(o-tolylideneimino)cyclohexane)(2,6-dichlorophenolato)]OTf CF3O3S(1-)*C36H36Cl2FeN3O(1+), orthorhombic

Guidance literature:

In acetonitrile; (N2); a soln. of Fe salt added to C6H9(NCHC6H4CH3)3, a soln. of Na salt added, stirred for 2 h; concd., filtered, evapd. (vac.), washed (Et2O), dried (vac.), crystd. byvapor diffusion of Et2O into a concd. THF soln. at -35°C for 2 m o; elem. anal.;

DOI:10.1021/ic101377u

Reference yield: 81.0%

C13H17NO4S + sodium 2,6-dichlorophenolate (29726-01-0) → 2,6-dichlorophenyl 2-(1-tosylpyrrolidin-2-yl)acetate

Guidance literature:

With caesium carbonate; 1,3-bis(mesityl)imidazolium chloride; HATU; In toluene; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2021.132337

upstream raw materials:

2,6-Dichlorophenol

Downstream raw materials:

[2-(2,6-Dichloro-phenoxy)-phenyl]-acetic acid

[2-(2,6-Dichloro-phenoxy)-5-methyl-phenyl]-acetic acid

1-(2,6-dichlorophenoxy)-4-nitrobenzene

2,2,4,4,6-Pentachloro-6-(2,6-dichloro-phenoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine