(Mes)2Ge(C(OEt)CHCHCH₂(t-Bu))

Base Information

• Chemical Name: (Mes)2Ge(C(OEt)CHCHCH₂(t-Bu))
• CAS No.: 1286755-67-6
• Molecular Formula: C₂₈H₄₀GeO
• Molecular Weight: 465.215
• Mol file: 1286755-67-6.mol

Synonyms:

Chemical Property of (Mes)2Ge(C(OEt)CHCHCH₂(t-Bu))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Mes)2Ge(C(OEt)CHCHCH₂(t-Bu))

There total 1 articles about (Mes)2Ge(C(OEt)CHCHCH₂(t-Bu)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimesitylvinylfluorogermane (143445-88-9) + tert.-butyl lithium (594-19-4) + 1-ethoxyacetylene (927-80-0) → (Mes)2Ge(C(OEt)CHCHCH2(t-Bu)) (1286755-67-6) + (Mes)2Ge(CHCH(t-Bu))(C(OEt)CHCH(CH2(t-Bu))GeH(Mes)2) (1286755-68-7)

Guidance literature:

In benzene-d6; byproducts: LiF; (ArN2); using Schlenk techniques; treatment with t-BuLi in pentane at -78°C, removal of C5H12 (vac.), dissolving in C6D6, addn. to HCCOEtwithin a few minutes at room temp.; removal of solvent by rotary evapn., removal of polymeric material by pptn. from CH2Cl2 soln. with MeCN, sepn. by chromy. on silica gel (8:2 hexanes/CH2Cl2 and then 5:5 hexanes/CH2Cl2); as oil;

DOI:10.1021/om200048p

upstream raw materials:

dimesitylvinylfluorogermane

tert.-butyl lithium

1-ethoxyacetylene