9-Dodecen-1-ol, (9E)-

Base Information

• Chemical Name: 9-Dodecen-1-ol, (9E)-
• CAS No.: 35237-62-8
• Molecular Formula: C12H24 O
• Molecular Weight: 184.322
• Hs Code.: 2905290000
• European Community (EC) Number: 809-980-1
• DSSTox Substance ID: DTXSID60885613
• Nikkaji Number: J422.334I,J610.210G
• Wikidata: Q67879657
• Metabolomics Workbench ID: 3117
• Mol file: 35237-62-8.mol

Synonyms:35237-62-8;9-Dodecen-1-ol, (9E)-;TRANS-9-DODECEN-1-OL;(E)-dodec-9-en-1-ol;9-Dodecen-1-ol;9-Dodecenol;9-Dodecen-1-ol, (E)-;9E-Dodecen-1-ol;dodeca-9-en-1-ol;(e)-9-dodecen-1-ol;9-Dodecen-1-ol, (Z)-;E-9-Dodecen-1-ol;AI3-35870;AI3-36900;9-Dodecenol, E;9-Dodecenol, trans;LMFA05000024;(9E)-Dodecen-1-ol;(E)9-Dodecen-1-ol;(E)-9-Dodecenyl alcohol;(9E)-9-Dodecen-1-ol;SCHEMBL517911;SCHEMBL832706;9-Dodecen-1-o1, (E)-;9-Dodecen-1-o1, (Z)-;DTXSID60885613;CHEBI:165512;GJNNIRNIXNLOJP-ONEGZZNKSA-N;MFCD00041710;9E-Dodecen-1-ol CAS 35237-62-8;Q67879657

Chemical Property of 9-Dodecen-1-ol, (9E)-

Chemical Property:

• Vapor Pressure: 0.000802mmHg at 25°C
• Boiling Point: 272.1°Cat760mmHg
• Flash Point: 100°C
• PSA: 20.23000
• Density: 0.846g/cm³
• LogP: 3.67560
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 184.182715385
• Heavy Atom Count: 13
• Complexity: 108

Purity/Quality:

99.3% ^*data from raw suppliers

(9E)-Dodecen-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=CCCCCCCCCO
• Isomeric SMILES: CC/C=C/CCCCCCCCO
• Uses: (9E)-Dodecen-1-ol is a compound found in the pheromone gland of codling moth, Cydia pomonella, and is important for the development of pheromone-based control methods.

Technology Process of 9-Dodecen-1-ol, (9E)-

There total 2 articles about 9-Dodecen-1-ol, (9E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dodec-9-yn-1-ol (71084-08-7) → 1-dodecyl alcohol (112-53-8) + (E)-9-dodecen-1-ol (35237-62-8) + (Z)-9-dodecenol (35148-18-6)

Guidance literature:

With triethanolamine; eosin y; In water; acetonitrile; at 20 ℃; for 2h; Irradiation; Inert atmosphere;

DOI:10.1039/c5cc08697c

Reference yield:

9-bromononan-1-ol (55362-80-6) → (E)-9-dodecen-1-ol (35237-62-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / acetonitrile

2: DMSO, NaH / tetrahydrofuran / 0.5 h

With sodium hydride; dimethyl sulfoxide; In tetrahydrofuran; acetonitrile;

DOI:10.1271/bbb1961.44.257

Reference yield: 98.0%

(E)-9-dodecen-1-ol (35237-62-8) + acetic anhydride (108-24-7) → (E)-9-dodecenyl acetate (35148-19-7)

Guidance literature:

With pyridine; dmap; at 25 ℃; for 0.5h;

DOI:10.1007/BF00961235

upstream raw materials:

9-bromononan-1-ol

dodec-9-yn-1-ol

Downstream raw materials:

(E)-9-dodecenyl acetate

Refernces

• 1、 Horiike,Tanouchi,Hirano. "A convenient method for synthesizing (Z)-alkenols and their acetates". . p. 257 - 261. Retrieved 2007/10/02.