Methyl 2-methyl-3-(trichlorosilyl)propanoate

Base Information

Chemical Name:Methyl 2-methyl-3-(trichlorosilyl)propanoate
CAS No.:3451-82-9
Molecular Formula:C5H9Cl3O2Si
Molecular Weight:235.57
Hs Code.:
DSSTox Substance ID:DTXSID90566004

Synonyms:3451-82-9;HTJFYHXRFXXFKG-UHFFFAOYSA-;DTXSID90566004;Methyl 2-methyl-3-(trichlorosilyl)propanoate;InChI=1/C5H9Cl3O2Si/c1-4(5(9)10-2)3-11(6,7)8/h4H,3H2,1-2H3

Suppliers and Price of Methyl 2-methyl-3-(trichlorosilyl)propanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Methyl 2-methyl-3-(trichlorosilyl)propanoate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:233.943739
Heavy Atom Count:11
Complexity:145

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C[Si](Cl)(Cl)Cl)C(=O)OC

Technology Process of Methyl 2-methyl-3-(trichlorosilyl)propanoate

There total 1 articles about Methyl 2-methyl-3-(trichlorosilyl)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 547-63-7,133320-07-7,67505-84-4
Methyl isobutyrate

: 3451-82-9
methyl 2-methyl-3-trichlorosilylpropionate

Guidance literature:: With trichlorosilane; bis(benzonitrile)dichloroplatinum(II); In chloroform; at 60 ℃; for 38h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/0022-328X(91)83201-E

Reference yield:

: 3451-82-9
methyl 2-methyl-3-trichlorosilylpropionate

: methyl 3-(4-acetylphenyl)-2-methylpropanoate

Guidance literature:: Multi-step reaction with 2 steps

1: CuF₂*2H₂O / diethyl ether / 0 - 20 °C

2: 42 percent / TBAF / Pd(PPh₃)4 / tetrahydrofuran / 18 h / 100 °C

With copper (II)-fluoride; tetrabutyl ammonium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; 1: Fluorination / 2: Alkylation;
DOI:10.1246/bcsj.70.437