Benzenamine, 4,4'-(phenylphosphinylidene)bis-

Base Information

Chemical Name:Benzenamine, 4,4'-(phenylphosphinylidene)bis-
CAS No.:3454-25-9
Molecular Formula:C18H17N2OP
Molecular Weight:308.32
Hs Code.:
DSSTox Substance ID:DTXSID70435067
Nikkaji Number:J658.792E
Wikidata:Q82249750

Synonyms:3454-25-9;Benzenamine, 4,4'-(phenylphosphinylidene)bis-;SCHEMBL63408;DTXSID70435067;bis(4-aminophenyl)phenylphosphine oxide

Suppliers and Price of Benzenamine, 4,4'-(phenylphosphinylidene)bis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzenamine, 4,4'-(phenylphosphinylidene)bis-

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:308.10785017
Heavy Atom Count:22
Complexity:366

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(=O)(C2=CC=C(C=C2)N)C3=CC=C(C=C3)N

Technology Process of Benzenamine, 4,4'-(phenylphosphinylidene)bis-

There total 4 articles about Benzenamine, 4,4'-(phenylphosphinylidene)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: Bis(4-aminophenyl)phenylphosphine

: 3454-25-9
bis(4-aminophenyl)(phenyl)phospate oxide

Guidance literature:: With dihydrogen peroxide; In acetone; for 4h; Heating;
DOI:10.1021/jo00116a042

Reference yield: 63.0%

: 916756-25-7
1,1'-[(phenylphosphoryl)di-4,1-phenylene]bis(2,5-dimethyl-1H-pyrrole)

: 3454-25-9
bis(4-aminophenyl)(phenyl)phospate oxide

Guidance literature:: With hydroxylamine hydrochloride; triethylamine; In ethanol; water; for 54h; Heating;
DOI:10.1055/s-2006-950185

Reference yield:

: 5044-24-6
1-(4-Bromo-phenyl)-2,5-dimethyl-1H-pyrrole

: 3454-25-9
bis(4-aminophenyl)(phenyl)phospate oxide

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / hexane; diethyl ether / 2 h / 0 °C

1.2: diethyl ether; hexane / 20 °C

1.3: 76 percent / aq. H₂O₂ / 4 h / Heating

2.1: 63 percent / NH₂OH*HCl; Et₃N / ethanol; H₂O / 54 h / Heating

With n-butyllithium; hydroxylamine hydrochloride; triethylamine; In diethyl ether; ethanol; hexane; water;
DOI:10.1055/s-2006-950185