Sodium bismuthate

Base Information

• Chemical Name: Sodium bismuthate
• CAS No.: 12232-99-4
• Deprecated CAS: 12125-43-8,33553-45-6,33553-45-6
• Molecular Formula: BiNaO3
• Molecular Weight: 279.97
• Hs Code.: 28419085
• European Community (EC) Number: 235-455-6
• UNII: 2PR2L7N425
• DSSTox Substance ID: DTXSID9065285
• Wikipedia: Sodium_bismuthate
• Mol file: 12232-99-4.mol

Synonyms:Sodium bismuthate;12232-99-4;Bismuth sodium trioxide;Sodium bismuthate(V);Bismuth sodium oxide (BiNaO3);sodium;oxido(dioxo)bismuth;Bismuthate (BiO31-), sodium;Sodium bismuthate (V);EINECS 235-455-6;SODIUM BISMUTH OXIDE;UNII-2PR2L7N425;Sodium Bismuthate (>80per cent);2PR2L7N425;MFCD00003474;BiO3.Na;Bismuthate (BiO31#-), sodium;Natriumwismutat;BiNaO3;Bismuth Sodium Oxide;Bi.Na.O;12232-99-4(Anhydrous;Sodium bismuthate, ACS reagent;Bismuth sodium oxide (NaBiO3);DTXSID9065285;SODIUM TRIOXOBISMUTHATE(V);PNYYBUOBTVHFDN-UHFFFAOYSA-N;SODIUM BISMUTHATE (NABIO3);SODIUM BISMUTHATE(V) [MI];Sodium bismuthate, p.a., 80.0%;AKOS015901588;SODIUM BISMUTH OXIDE (NABIO3);SODIUM BISMUTHATE(V) (NABIO3);LS-145519;Sodium bismuthate, Vetec(TM) reagent grade, 80%

Chemical Property of Sodium bismuthate

Chemical Property:

• Appearance/Colour: yellow-brown powder
• PSA: 57.20000
• LogP: -0.35640
• Storage Temp.: Room Temperature
• Sensitive.: Hygroscopic
• Solubility.: Aqueous Acid (Slightly, Heated)
• Water Solubility.: Soluble in aqueous acid. Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 279.95491
• Heavy Atom Count: 5
• Complexity: 49.8

Purity/Quality:

99% ^*data from raw suppliers

SodiumBismuthate(>80%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [O-][Bi](=O)=O.[Na+]
• Uses: Oxidizer; determination of manganese in iron and steel. For the determination of manganese in iron and steel, etc., the manganese being oxidized by it in hot HNO3 or H2SO4 solution to permanganate. Sodium Bismuthate, is an inorganic compound, which is a strong oxidiser. Sodium Bismuthate converts almost any manganese compound to permanganate, which is easily assayed spectrophotometrically.

Refernces

Cleavage of Unsaturated α-Ketols to ω-Oxo-α,β-unsaturated Acids

10.1021/jo00060a040

The research focuses on the cleavage of unsaturated α-ketols to o-oxo-α,β-unsaturated acids, with the aim of developing an enantioselective synthesis of cyclic systems bearing contiguous quaternary centers, particularly those with gem-dimethyl groups. The study concludes that sodium periodate is the most effective reagent for this cleavage, outperforming other common oxidizing agents like sodium bismuthate, manganese dioxide, and lead tetraacetate, in terms of yield and efficiency. The combination of this cleavage reaction with a rhodium(I)-mediated decarbonylation of o-oxo-α,β-unsaturated esters derived from polycyclic systems was found to be a successful approach for the synthesis of the desired cyclic systems. Key chemicals used in the process include sodium periodate, sodium bismuthate, manganese dioxide, lead tetraacetate, and various α-ketols, among others, with the research providing detailed procedures and spectral data for the synthesized compounds.

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