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Potassium (4-tert-butylphenyl)methanide

Base Information
  • Chemical Name:Potassium (4-tert-butylphenyl)methanide
  • CAS No.:3605-35-4
  • Molecular Formula:C11H15K
  • Molecular Weight:186.338
  • Hs Code.:
  • DSSTox Substance ID:DTXSID20561123
  • Mol file:3605-35-4.mol
Potassium (4-tert-butylphenyl)methanide

Synonyms:3605-35-4;POTASSIUM (4-TERT-BUTYLPHENYL)METHANIDE;DTXSID20561123

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Chemical Property of Potassium (4-tert-butylphenyl)methanide
Chemical Property:
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:1
  • Rotatable Bond Count:1
  • Exact Mass:186.08108196
  • Heavy Atom Count:12
  • Complexity:116
Purity/Quality:
Safty Information:
  • Pictogram(s):  
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MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:CC(C)(C)C1=CC=C(C=C1)[CH2-].[K+]
Technology Process of Potassium (4-tert-butylphenyl)methanide

There total 1 articles about Potassium (4-tert-butylphenyl)methanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
4-tert-butyltoluene; With potassium tert-butylate; at -35 ℃; for 0.333333h;
With n-butyllithium; In hexane; at -35 - 20 ℃; for 3h;
DOI:10.1021/acs.organomet.5b00212
Guidance literature:
In tetrahydrofuran; under Ar or N2, 5.37 equiv. of K-compd. in THF was added to THF soln. of1.82 equiv. of metal-compd. at -50 °C, stirring for 2 h at 0 .de gree.C; ppt. was centrifuged off, soln. was concd., pentane was layered, slow cooling to -30 °C, elem. anal.;
DOI:10.1515/znb-2008-0307
upstream raw materials:

4-tert-butyltoluene

Downstream raw materials:

(4-tBuC6H4CH2)3La(III)

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