2-Benzyl-2-methyloxirane

Base Information

• Chemical Name: 2-Benzyl-2-methyloxirane
• CAS No.: 36099-42-0
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• DSSTox Substance ID: DTXSID40451173
• Nikkaji Number: J1.008.668J
• Mol file: 36099-42-0.mol

Synonyms:2-benzyl-2-methyloxirane;36099-42-0;Oxirane, 2-methyl-2-(phenylmethyl)-;2-methyl-2-benzyl-oxirane;SCHEMBL2525239;DTXSID40451173;HXDOYMSDQUBFHJ-UHFFFAOYSA-N;rac-2-methyl-3-phenyl-1,2-epoxypropane;EN300-1869554

Chemical Property of 2-Benzyl-2-methyloxirane

Chemical Property:

• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 148.088815002
• Heavy Atom Count: 11
• Complexity: 138

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CO1)CC2=CC=CC=C2

Technology Process of 2-Benzyl-2-methyloxirane

There total 7 articles about 2-Benzyl-2-methyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

→ (+/-)-2-methyl-3-phenyl-1,2-epoxypropane (36099-42-0)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 22 ℃;

Reference yield: 71.0%

2-methyl-1-phenyl-2-propene (3290-53-7) → (+/-)-2-methyl-3-phenyl-1,2-epoxypropane (36099-42-0) + rac-2-methyl-3-phenyl-1,2-epoxpropane

Guidance literature:

With dihydrogen peroxide; potassium carbonate; In methanol; ethyl acetate; acetonitrile;

Reference yield: 70.0%

diiodomethane (75-11-6) + 1-phenyl-acetone (103-79-7,136675-26-8) → (+/-)-2-methyl-3-phenyl-1,2-epoxypropane (36099-42-0)

Guidance literature:

With methyllithium; In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; for 1.5h;

DOI:10.1016/S0040-4020(01)00890-0

upstream raw materials:

chloroacetone

benzylmagnesium chloride

diiodomethane

1-phenyl-acetone

Downstream raw materials:

2,6-dimethyl-1-phenyl-hept-5-en-2-ol

1-Diaethylamino-2-benzyl-propanol-⁽²⁾

2-benzylpropionaldehyde

rac-2-methyl-3-phenyl-1,2-propanediol