4-METHOXYPHENETHYLMAGNESIUM BROMIDE

Base Information

• Chemical Name: 4-METHOXYPHENETHYLMAGNESIUM BROMIDE
• CAS No.: 36278-54-3
• Molecular Formula: C9H11BrMgO
• Molecular Weight: 239.395
• Hs Code.: 2931900090
• Mol file: 36278-54-3.mol

Synonyms:Magnesium,bromo[2-(4-methoxyphenyl)ethyl];4-methoxyphenethylmagnesium bromide;2-p-methoxyphenylethylmagnesium bromide;4-Methoxyphenethylmagnesium bromide 0.5 M in Tetrahydrofuran;bromure de 2(4-methoxyphenyl)ethylmagnesium;4-methoxyphenylethylmagnesium bromide;2-(4-methoxyphenyl)ethylmagnesium bromide;

Chemical Property of 4-METHOXYPHENETHYLMAGNESIUM BROMIDE

Chemical Property:

• PSA: 9.23000
• LogP: -0.81170

Purity/Quality:

97% ^*data from raw suppliers

4-Methoxyphenethylmagnesiumbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-METHOXYPHENETHYLMAGNESIUM BROMIDE

There total 3 articles about 4-METHOXYPHENETHYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

4-methoxyphenethyl bromide (14425-64-0) → 2-(4-methoxyphenyl)ethylmagnesium bromide (36278-54-3)

Guidance literature:

With iodine; magnesium; In tetrahydrofuran; for 1h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1002/anie.201800792

Reference yield:

4-methoxyphenethyl bromide (14425-64-0) + magnesium (7439-95-4) → 2-(4-methoxyphenyl)ethylmagnesium bromide (36278-54-3)

Guidance literature:

In tetrahydrofuran;

Reference yield:

→ 5-(4-methoxyphenyl)-1-pentene (51125-16-7) + 2-(4-methoxyphenyl)ethylmagnesium bromide (36278-54-3)

Guidance literature:

upstream raw materials:

4-methoxyphenethyl bromide

magnesium

Downstream raw materials:

cis-3-(2-p-Methoxyphenylethyl)-2,3,4-trimethylcyclohexanone

trans-3-(2-p-methoxyphenylethyl)-2,3,4-trimethylcyclohexanone

1-trimethylsilyloxy-3-[2-(4-methoxyphenyl)ethyl]-1-cyclohexene

3-(4-methoxyphenyl)propanoic acid