Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)-

Base Information

Chemical Name:Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)-
CAS No.:364337-19-9
Molecular Formula:C18H20O3Se
Molecular Weight:363.315
Hs Code.:
DSSTox Substance ID:DTXSID20463572
Wikidata:Q82288512
Mol file:364337-19-9.mol

Synonyms:364337-19-9;Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)-;DTXSID20463572

Suppliers and Price of Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:9
Exact Mass:364.05777
Heavy Atom Count:22
Complexity:297

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)COC(CC[Se]C2=CC=CC=C2)C=O
Isomeric SMILES:COC1=CC=C(C=C1)CO[C@H](CC[Se]C2=CC=CC=C2)C=O

Technology Process of Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)-

There total 6 articles about Butanal, 2-[(4-methoxyphenyl)methoxy]-4-(phenylseleno)-, (2R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 364337-18-8
methyl (2R)-2-p-methoxybenzyloxy-4-phenylselanylbutanoate

: 364337-19-9
(2R)-2-p-methoxybenzyloxy-4-phenylselanylbutanal

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -78 ℃; for 0.333333h;
DOI:10.1021/ol016343z

Reference yield:

: 364337-18-8
methyl (2R)-2-p-methoxybenzyloxy-4-phenylselanylbutanoate

: 364337-19-9
(2R)-2-p-methoxybenzyloxy-4-phenylselanylbutanal

: (2S)-2-p-methoxybenzyloxy-4-phenylselanylbutanal

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -78 ℃; for 0.333333h; Title compound not separated from byproducts;
DOI:10.1021/jo035065+

Reference yield:

: 1666-13-3
diphenyl diselenide

: 364337-19-9
(2R)-2-p-methoxybenzyloxy-4-phenylselanylbutanal

Guidance literature:: Multi-step reaction with 4 steps

1.1: NaH / tetrahydrofuran / 1 h / 60 °C

1.2: 18-crown-6 / tetrahydrofuran / 2 h / 20 °C

2.1: 8.42 g / diethyl ether / 20 °C

3.1: 70 percent / camphorsulfonic acid / CH₂Cl₂ / 24 h / 20 °C

4.1: DIBAL-H / toluene / 0.33 h / -78 °C

With camphor-10-sulfonic acid; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; diethyl ether; dichloromethane; toluene;
DOI:10.1021/jo035065+