1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate

Base Information

Chemical Name:1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate
CAS No.:3709-22-6
Molecular Formula:C14H16O4
Molecular Weight:248.279
Hs Code.:
DSSTox Substance ID:DTXSID101189692

Synonyms:DTXSID101189692;1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate;3709-22-6

Suppliers and Price of 1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:248.10485899
Heavy Atom Count:18
Complexity:315

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1(CC1CC2=CC=CC=C2)C(=O)OC

Technology Process of 1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate

There total 4 articles about 1,1-Dimethyl 2-(phenylmethyl)-1,1-cyclopropanedicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 300-57-2,57807-91-7
allylbenzene

: 145838-86-4
bis(methoxycarbonyl)(phenyliodinio)methanide

: 3709-22-6
dimethyl 2-(phenylmethyl)cyclopropane-1,1-dicarboxylate

Guidance literature:: dirhodium tetraacetate; at 120 ℃; for 0.0166667h;
DOI:10.1055/s-2001-18750

Reference yield:

: 3709-33-9
1-benzyl-6,6-dimethyl-5,7-dioxaspiro[2.5]octane-4,8-dione

: 3709-22-6
dimethyl 2-(phenylmethyl)cyclopropane-1,1-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: aq. NaOH / ethanol

With sodium hydroxide; In ethanol;
DOI:10.1007/BF00904733