Bicyclo[3.2.1]oct-6-en-3-one

Base Information

• Chemical Name: Bicyclo[3.2.1]oct-6-en-3-one
• CAS No.: 3721-60-6
• Molecular Formula: C8H10O
• Molecular Weight: 122.16400
• Hs Code.: 2914299000
• Mol file: 3721-60-6.mol

Synonyms:Bicyclo<3,2,1>octen-6on-3;3-Oxo-bicyclo<3.2.1>oct-6-en;Bicyclo<3.2.1>-oct-6-en-3-on;bicyclo<3.2.1>oct-6-en-3-one;

Chemical Property of Bicyclo[3.2.1]oct-6-en-3-one

Chemical Property:

• Melting Point: 98-100 °C
• Boiling Point: 120-140 °C(Press: 11 Torr)
• PSA: 17.07000
• Density: 1.083±0.06 g/cm3(Predicted)
• LogP: 1.54160

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bicyclo[3.2.1]oct-6-en-3-one

There total 15 articles about Bicyclo[3.2.1]oct-6-en-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

endo-2,endo-4-Dichlorbicyclo<3.2.1>oct-6-en-3-on (115319-13-6) → bicyclo<3.2.1>oct-6-en-3-one (3721-60-6)

Guidance literature:

With ammonium chloride; copper(l) chloride; zinc; In methanol; for 3h; Ambient temperature;

Reference yield:

2,4-Dibromo-bicyclo[3.2.1]oct-6-en-3-one (63127-25-3) → bicyclo<3.2.1>oct-6-en-3-one (3721-60-6)

Guidance literature:

With copper; ammonium chloride; zinc; In methanol; at -80 - 20 ℃;

DOI:10.1002/adsc.200505375

Reference yield:

3-bromo-2-methoxypropene (26562-24-3) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → bicyclo<3.2.1>oct-6-en-3-one (3721-60-6)

Guidance literature:

With silver trifluoroacetate; sodium carbonate; In methylbutane; benzene;

DOI:10.1021/ja00785a057

upstream raw materials:

3-bromo-2-methoxypropene

cyclopenta-1,3-diene

propargyl bromide

1,1,3,3-tetrabromoacetone

Downstream raw materials:

endo-Bicyclo<3.2.1>octen-6-yl-3-p-tosylat

Tricyclo<3.1.1.0^3,6>heptan-6-carbonsaeurechlorid

2-(endo-Bicyclo<3.2.1>oct-6-en-3-yl)ethyl-1,1-d2-p-brombenzolsulfonat

2-(endo-Bicyclo<3.2.1>oct-6-en-3-yl)ethyl-p-brombenzolsulfonat