trans-2,5-Dimethyloxolane

Base Information

Chemical Name:trans-2,5-Dimethyloxolane
CAS No.:2390-94-5
Molecular Formula:C₆H₁₂O
Molecular Weight:100.161
Hs Code.:
UNII:XV3745SMWL
DSSTox Substance ID:DTXSID901014219
Nikkaji Number:J313.943C
Wikidata:Q24734527
Mol file:2390-94-5.mol

Synonyms:trans-2,5-Dimethyloxolane;2390-94-5;TRANS-2,5-DIMETHYLTETRAHYDROFURAN;rel-trans-2,5-Dimethyltetrahydrofuran;XV3745SMWL;2,5-Dimethyloxolane, trans-;Furan, tetrahydro-2,5-dimethyl-, trans-;(2R,5R)-2,5-dimethyloxolane;Rel-(2R,5R)-2,5-dimethyltetrahydrofuran;starbld0001006;UNII-XV3745SMWL;2,5-Dimethyltetrahydrofuran #;SCHEMBL9681629;OXMIDRBAFOEOQT-PHDIDXHHSA-N;DTXSID901014219;2alpha,5beta-Dimethyltetrahydrofuran;(2R,5R)-2,5-Dimethyl-tetrahydro-furan;trans-(+/-)-2,5-Dimethyltetrahydrofuran;TRANS-TETRAHYDRO-2,5-DIMETHYLFURAN;trans-(.+/-.)-2,5-Dimethyltetrahydrofuran;(+/-)-TRANS-2,5-DIMETHYLTETRAHYDROFURAN;(+/-)-TRANS-TETRAHYDRO-2,5-DIMETHYLFURAN;Furan, tetrahydro-2,5-dimethyl-, trans-(.+/-.)-;Q24734527;FURAN, TETRAHYDRO-2,5-DIMETHYL-, (2R,5R)-REL-

Suppliers and Price of trans-2,5-Dimethyloxolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
rel-trans-2,5-Dimethyltetrahydrofuran
1g
$ 1025.00

TRC
rel-trans-2,5-Dimethyltetrahydrofuran
100mg
$ 160.00

Total 4 raw suppliers

Chemical Property of trans-2,5-Dimethyloxolane

Chemical Property:

Boiling Point:91°Cat760mmHg
Flash Point:26.7°C
Density:0.836g/cm³
XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:100.088815002
Heavy Atom Count:7
Complexity:53.2

Purity/Quality:

99% ^*data from raw suppliers

rel-trans-2,5-Dimethyltetrahydrofuran ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1CCC(O1)C
Isomeric SMILES:C[C@@H]1CC[C@H](O1)C
Uses rel-trans-2,5-Dimethyltetrahydrofuran is a chiral reagent used in the synthesis of solvated monomeric and dimeric complexes of lithium anilide. Dihydrofuranyl derivative.

Technology Process of trans-2,5-Dimethyloxolane

There total 3 articles about trans-2,5-Dimethyloxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 152564-05-1
(2S,5R)-5-acetoxyhexane-2-yl-4-methylbenzenesulfonate

: 1003-38-9,2144-41-4,2390-94-5,38484-59-2,79083-02-6,79083-03-7,81422-48-2,117064-01-4
(-)-(R,R)-2,5-dimethyltetrahydrofurane

Guidance literature:: With sodium; In ethylene glycol; at 0 ℃; for 32h; Yield given;
DOI:10.1021/jo00075a056

Reference yield:

: 17299-07-9
(2R,5R)-2,5-hexanediol

: 1003-38-9,2144-41-4,2390-94-5,38484-59-2,79083-02-6,79083-03-7,81422-48-2,117064-01-4
(-)-(R,R)-2,5-dimethyltetrahydrofurane

: 2144-41-4
(2R,5S)-2,5-dimethyltetrahydrofuran

Guidance literature:: With carbon dioxide; In water; at 249.84 ℃; under 121512 Torr; Reagent/catalyst; stereoselective reaction; Kinetics; Inert atmosphere;
DOI:10.1016/j.cattod.2011.07.025

Reference yield:

: 38484-59-2
(+/-)-trans-2,5-dimethyltetrahydrofuran

: 1003-38-9,2144-41-4,2390-94-5,38484-59-2,79083-02-6,79083-03-7,81422-48-2,117064-01-4
(-)-(R,R)-2,5-dimethyltetrahydrofurane

: 81422-48-2
(+)-(2S,5S)-trans-2,5-dimethyltetrahydrofuran

Guidance literature:: Thermodynamic data; enantiomeric resolution by complexation gas chromatography on bis<(1R)-3-(heptafluorobutyryl)camphorates> of Ni(II), Co(II), Mn(II) in squalane at 60 deg C, separation factors, thermodynamic parameters of enantiomer discrimination (-Δ(ΔG⁰));
DOI:10.1021/ja00390a031