3-(Bromomethyl)benzofuran

Base Information

Chemical Name:3-(Bromomethyl)benzofuran
CAS No.:38281-49-1
Molecular Formula:C9H7BrO
Molecular Weight:211.058
Hs Code.:
European Community (EC) Number:816-811-5
DSSTox Substance ID:DTXSID00491575
Wikidata:Q82336299
Mol file:38281-49-1.mol

Synonyms:3-(bromomethyl)benzofuran;38281-49-1;3-(Bromomethyl)-1-benzofuran;3-Bromomethylbenzofuran;3-bromomethyl-benzofuran;SCHEMBL3281151;DTXSID00491575;AEWASAYNGKXLBK-UHFFFAOYSA-N;AKOS013449436;DS-19052;EN300-333669

Suppliers and Price of 3-(Bromomethyl)benzofuran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 3-(Bromomethyl)benzofuran

Chemical Property:

XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:209.96803
Heavy Atom Count:11
Complexity:138

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C(=CO2)CBr

Technology Process of 3-(Bromomethyl)benzofuran

There total 11 articles about 3-(Bromomethyl)benzofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 4687-23-4
3-hydroxymethylbenzofuran

: 38281-49-1
3-bromomethylbenzofuran

Guidance literature:: With phosphorus tribromide; In diethyl ether; at 0 ℃; for 0.5h;

Reference yield: 68.0%

: 52536-39-7
2-(prop-2-ynyloxy)benzenediazonium tetrafluoroborate

: 38281-49-1
3-bromomethylbenzofuran

Guidance literature:: 2-(prop-2-ynyloxy)benzenediazonium tetrafluoroborate; With hydrogen bromide; In water; acetone; at 0 ℃; for 0.0833333h; Inert atmosphere;

With tert.-butylnitrite; In water; acetone; at 0 ℃; for 0.25h;

With sodium iodide; In water; acetone; at 0 - 60 ℃; for 9h;

Reference yield:

: 194278-43-8
benzofuran-3-carboxylic acid ethyl ester

: 38281-49-1
3-bromomethylbenzofuran

Guidance literature:: Multi-step reaction with 2 steps

1: 444 mg / DIBAL-H / CH₂Cl₂; hexane / 4 h / -78 - 20 °C

2: 48 percent / PPh₃, Br₂ / CCl₄ / 1.5 h / Ambient temperature

With bromine; diisobutylaluminium hydride; triphenylphosphine; In tetrachloromethane; hexane; dichloromethane;
DOI:10.1021/jm970265x