4,4'-(1,10-Decanediyl)dioxydianiline

Base Information

• Chemical Name: 4,4'-(1,10-Decanediyl)dioxydianiline
• CAS No.: 38324-63-9
• Molecular Formula: C22H32N2O2
• Molecular Weight: 356.508
• Hs Code.: 2922299090
• DSSTox Substance ID: DTXSID00544272
• Nikkaji Number: J740.324K
• Wikidata: Q82421346
• Mol file: 38324-63-9.mol

Synonyms:4,4'-(1,10-decanediyl)dioxydianiline;38324-63-9;4-[10-(4-aminophenoxy)decoxy]aniline;SCHEMBL4019814;1,10-bis(p-aminophenoxy)decane;DTXSID00544272;1,10-Bis(4-Aminophenoxy)decane;NGMJQNYIDZLGFP-UHFFFAOYSA-N;4,4'-[Decane-1,10-diylbis(oxy)]dianiline

Chemical Property of 4,4'-(1,10-Decanediyl)dioxydianiline

Chemical Property:

• Boiling Point: 517oC at 760 mmHg
• Flash Point: 274.4oC
• PSA: 70.50000
• Density: 1.073g/cm3
• LogP: 6.59200
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 13
• Exact Mass: 356.246378268
• Heavy Atom Count: 26
• Complexity: 292

Purity/Quality:

98%min ^*data from raw suppliers

4-[10-(4-Aminophenoxy)decoxy]aniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1N)OCCCCCCCCCCOC2=CC=C(C=C2)N

Technology Process of 4,4'-(1,10-Decanediyl)dioxydianiline

There total 9 articles about 4,4'-(1,10-Decanediyl)dioxydianiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

1,10-bis(4-nitrophenoxy)decane (38201-80-8) → 4,4'-(decane-1,10-diylbis(oxy))dianiline (38324-63-9)

Guidance literature:

With palladium 10% on activated carbon; hydrazine hydrate; In ethanol; dichloromethane; for 24h;

DOI:10.1039/c0cc00521e

Reference yield:

4-nitrophenol sodium salt (824-78-2) → 4,4'-(decane-1,10-diylbis(oxy))dianiline (38324-63-9)

Guidance literature:

Multi-step reaction with 2 steps

1: dimethylformamide / 10 h / Heating

2: H₂ / 5percent Pd/C / tetrahydrofuran; methanol / 2280 Torr

With hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;

DOI:10.1021/jm00149a032

Reference yield:

1,10-Bis-(p-acetamidophenoxy)-decan (197456-67-0) → 4,4'-(decane-1,10-diylbis(oxy))dianiline (38324-63-9)

Guidance literature:

With hydrogenchloride;

DOI:10.1021/ja00512a020

upstream raw materials:

1,10-Bis-(p-acetamidophenoxy)-decan

1,10-bis(4-nitrophenoxy)decane

4-acetaminophenol

4-nitrophenol sodium salt

Downstream raw materials:

(E)-4-(10-(4-((4-(trifluoromethyl)phenyl)diazenyl)phenoxy)decyloxy)aniline