3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

Base Information

Chemical Name:3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one
CAS No.:38335-10-3
Molecular Formula:C₉H₁₂O₂
Molecular Weight:152.193
Hs Code.:
DSSTox Substance ID:DTXSID30559051
Mol file:38335-10-3.mol

Synonyms:38335-10-3;SCHEMBL5528743;3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one;DTXSID30559051

Suppliers and Price of 3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of 3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

Chemical Property:

XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:152.083729621
Heavy Atom Count:11
Complexity:236

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12CC3CC1C(C3)OC2=O

Technology Process of 3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

There total 1 articles about 3-Methylhexahydro-2H-3,5-methanocyclopenta[b]furan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 22911-65-5
endo-2-methylbicyclo[2.2.1]hept-5-ene-2-carbonitrile

: 38335-10-3
(+/-)-3-methyl-hexahydro-3,5-methano-cyclopenta[b]furan-2-one

: 118918-62-0
exo-6-Hydroxy-exo-2-methylbicyclo<2.2.1>heptan-endo-2-carbonitril

: 118918-63-1
exo-5-Hydroxy-exo-2-methylbicyclo<2.2.1>heptan-endo-2-carbonitril

: 118867-84-8
5-Oxo-exo-2-methylbicyclo<2.2.1>heptan-endo-2-carbonitril

Guidance literature:: With diethylene glycol dimethyl ether; Na-boranate; boron trifluoride diethyl etherate; chromic acid; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1) ether, 0 deg C, 1 h; 2) ether, 0 deg C;

Reference yield:

: 38335-10-3
(+/-)-3-methyl-hexahydro-3,5-methano-cyclopenta[b]furan-2-one

: 87729-26-8
2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / LiAlH₄ / diethyl ether; tetrahydrofuran / 1.) 0 deg C, 2.) 18 h, room temperature

2: 47 percent / Pyridine / diethyl ether / 2 h / -20 °C

With pyridine; lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether;
DOI:10.1021/jo00177a015

Reference yield:

: 38335-10-3
(+/-)-3-methyl-hexahydro-3,5-methano-cyclopenta[b]furan-2-one

: 87729-25-7
6-exo-(Benzoyloxy)-2-endo-<(benzoyloxy)methyl>-2-exo-methylbicyclo<2.2.1>heptane

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / LiAlH₄ / diethyl ether; tetrahydrofuran / 1.) 0 deg C, 2.) 18 h, room temperature

2: 47 percent / Pyridine / diethyl ether / 2 h / -20 °C

3: 14 percent / Triphenylphosphine, Diethyl azodicarboxylate / benzene / 3 h / 60 - 65 °C

With pyridine; lithium aluminium tetrahydride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; benzene;
DOI:10.1021/jo00177a015