methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate

Base Information

Chemical Name:methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate
CAS No.:38555-41-8
Molecular Formula:C7H10O3S
Molecular Weight:174.221
Hs Code.:2934999090
European Community (EC) Number:857-899-5
DSSTox Substance ID:DTXSID901250445
Mol file:38555-41-8.mol

Synonyms:38555-41-8;methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate;METHYL 3-OXOTHIANE-2-CARBOXYLATE;Methyl 3-oxotetrahydrothiopyran-2-carboxylate;METHYL TETRAHYDRO-3-OXO-6H-THIOPYRAN-2-CARBOXYLATE;starbld0038973;SCHEMBL621079;CEDARSWTTYNIHA-UHFFFAOYSA-N;DTXSID901250445;methyl 3-oxo-2,3,4,5-tetrahydro-6H-thiopyran-2-carboxylate;AKOS015900865;AT37646;DB-069701;EN300-6473204;methyl-3-oxo2,3,4,5-tetrahydro-6H-thiopyran-2-carboxylate;methyl-3-oxo-2,3,4,5-tetrahydro-6H-thiopyran-2-carboxylate

Suppliers and Price of methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AK Scientific
Methyl3-oxotetrahydro-2H-thiopyran-2-carboxylate
1g
$ 773.00

AK Scientific
Methyl3-oxotetrahydro-2H-thiopyran-2-carboxylate
100mg
$ 289.00

Total 2 raw suppliers

Chemical Property of methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate

Chemical Property:

Boiling Point:266℃
Flash Point:124℃
PSA：68.67000
Density:1.244
LogP:0.62410
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:174.03506535
Heavy Atom Count:11
Complexity:179

Purity/Quality:

98%Min ^*data from raw suppliers

Methyl3-oxotetrahydro-2H-thiopyran-2-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1C(=O)CCCS1

Technology Process of methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate

There total 4 articles about methyl 3-oxotetrahydro-2H-thiopyran-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 38555-40-7
methyl 4-{[2-(methyloxy)-2-oxoethyl]thio}butanoate

: 38555-41-8
methyl 3-oxo-2,3,4,5-tetrahydro-6H-thiopyran-2-carboxylate

Guidance literature:: In tetrahydrofuran; diethyl ether;

Reference yield:

: 38555-40-7
methyl 4-{[2-(methyloxy)-2-oxoethyl]thio}butanoate

: 38555-41-8
methyl 3-oxo-2,3,4,5-tetrahydro-6H-thiopyran-2-carboxylate

: 1369098-29-2
methyl 3-oxotetrahydro-2H-thiopyran-4-carboxylate

Guidance literature:: With sodium methylate; In toluene; at 20 - 105 ℃; for 3h;
DOI:10.1016/j.bmcl.2013.03.104

Reference yield:

: 38555-40-7
methyl 4-{[2-(methyloxy)-2-oxoethyl]thio}butanoate

: 38555-41-8
methyl 3-oxo-2,3,4,5-tetrahydro-6H-thiopyran-2-carboxylate

: 40389-61-5
2-carbomethoxy-3-oxo tetrahydrothiine

Guidance literature:: methyl 4-{[2-(methyloxy)-2-oxoethyl]thio}butanoate; With potassium tert-butylate; In diethyl ether; at 0 - 20 ℃; for 4h;

With water; acetic acid; In diethyl ether;
DOI:10.1021/acs.joc.7b00172