methyl hydrogen dodecylphosphonate

Base Information

• Chemical Name: methyl hydrogen dodecylphosphonate
• CAS No.: 388625-44-3
• Molecular Formula: C₁₃H₂₉O₃P
• Molecular Weight: 264.345
• Mol file: 388625-44-3.mol

Synonyms:

Chemical Property of methyl hydrogen dodecylphosphonate

Chemical Property:

• Vapor Pressure: 5.52E-06mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl hydrogen dodecylphosphonate

There total 4 articles about methyl hydrogen dodecylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sodium methyl dodecylphosphonate → methyl dodecylmonophosphonic acid (388625-44-3)

Guidance literature:

With Amberlite IR₁₂₀; In methanol;

DOI:10.1021/ma047912w

Reference yield:

dodecylphosphonate de dimethyle (16693-57-5) → methyl dodecylmonophosphonic acid (388625-44-3)

Guidance literature:

With sodium iodide; In butanone; at 90 ℃; for 16h;

DOI:10.1080/10426500210664

Reference yield:

1-dodecene (112-41-4,25067-08-7,62132-67-6) → methyl dodecylmonophosphonic acid (388625-44-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 70 percent / di-tert-butyl peroxide / 10 h / 135 °C

2: 95 percent / NaI / butan-2-one / 12 h / 100 °C

3: 100 percent / Amberlite IR₁₂₀ / methanol

With di-tert-butyl peroxide; Amberlite IR₁₂₀; sodium iodide; In methanol; butanone;

DOI:10.1021/ma047912w

upstream raw materials:

dodecylphosphonate de dimethyle

1-dodecene

Refernces

• 1、 Gaboyard,Hervaud,Boutevin. "Synthesis and structural study of long-chain hydrocarbon alkylphosphonic acids". . p. 877 - 891. Retrieved 2007/10/03.