[(1-Phenylethyl)selanyl]benzene

Base Information

• Chemical Name: [(1-Phenylethyl)selanyl]benzene
• CAS No.: 39192-26-2
• Molecular Formula: C14H14Se
• Molecular Weight: 261.225
• DSSTox Substance ID: DTXSID30501979
• Nikkaji Number: J966.589G
• Mol file: 39192-26-2.mol

Synonyms:[(1-Phenylethyl)selanyl]benzene;39192-26-2;DTXSID30501979

Chemical Property of [(1-Phenylethyl)selanyl]benzene

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 262.02607
• Heavy Atom Count: 15
• Complexity: 166

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C1=CC=CC=C1)[Se]C2=CC=CC=C2

Technology Process of [(1-Phenylethyl)selanyl]benzene

There total 18 articles about [(1-Phenylethyl)selanyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

diphenyl diselenide (1666-13-3) + (1-bromoethyl)benzne (585-71-7,38661-81-3) → 1-phenylethyl phenyl selenide (39192-26-2)

Guidance literature:

With indium iodide; In dichloromethane; at 20 ℃; for 0.116667h;

DOI:10.1021/ol034178c DOI:10.1021/jo0493727

Reference yield: 82.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + bromobenzene (108-86-1,52753-63-6) → 1-phenylethyl phenyl selenide (39192-26-2)

Guidance literature:

bromobenzene; With magnesium; In tetrahydrofuran; at 45 ℃; for 1h; Inert atmosphere;

With selenium; In tetrahydrofuran; for 0.5h; Inert atmosphere;

styrene; With copper(l) iodide; L-proline; In tetrahydrofuran; water; toluene; at 85 ℃; for 8h; regioselective reaction; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.08.046

Reference yield: 69.0%

1-Phenylethanol (98-85-1,13323-81-4) + phenyl trimethylsilyl selenide (33861-17-5) → 1-phenylethyl phenyl selenide (39192-26-2)

Guidance literature:

With aluminum tri-bromide; In dichloromethane; for 0.166667h; Ambient temperature;

DOI:10.1248/cpb.46.1311

upstream raw materials:

phenyl selenocyanate

1-Phenylethanol

diphenyl diselenide

C₂₂H₂₃NO₄S₂

Downstream raw materials:

styrene

ethylbenzene

(S)-phenyl(1-phenylethyl)selane

(R)-phenyl(1-phenylethyl)selane