2-Propenoic acid, 3-[(1S,2S,3R)-2-[(acetyloxy)methyl]-3-[[[(1,1-dimethylethyl)diphenylsilyl] oxy]methyl]cyclopropyl]-, ethyl ester, (2E)-

Base Information

Chemical Name:2-Propenoic acid, 3-[(1S,2S,3R)-2-[(acetyloxy)methyl]-3-[[[(1,1-dimethylethyl)diphenylsilyl] oxy]methyl]cyclopropyl]-, ethyl ester, (2E)-
CAS No.:392655-87-7
Molecular Formula:C₂₈H₃₆O₅Si
Molecular Weight:480.676
Hs Code.:
Mol file:392655-87-7.mol

Synonyms:

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Chemical Property of 2-Propenoic acid, 3-[(1S,2S,3R)-2-[(acetyloxy)methyl]-3-[[[(1,1-dimethylethyl)diphenylsilyl] oxy]methyl]cyclopropyl]-, ethyl ester, (2E)-

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Technology Process of 2-Propenoic acid, 3-[(1S,2S,3R)-2-[(acetyloxy)methyl]-3-[[[(1,1-dimethylethyl)diphenylsilyl] oxy]methyl]cyclopropyl]-, ethyl ester, (2E)-

There total 4 articles about 2-Propenoic acid, 3-[(1S,2S,3R)-2-[(acetyloxy)methyl]-3-[[[(1,1-dimethylethyl)diphenylsilyl] oxy]methyl]cyclopropyl]-, ethyl ester, (2E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (1R,5S,6S)-((E)-6-Propenyl)-3-oxa-bicyclo[3.1.0]hexan-2-one

: 392655-87-7
(2'S,3'R,3S)-ethyl 3-[2'-acetoxymethyl-3'-(tert-butyldiphenylsilanyloxymethyl)cyclopropyl]acrylate

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / LiAlH₄ / tetrahydrofuran / 20 °C

2: 97 percent / Pseudomonas fluorescens lipase AK / benzene / 2.5 h / 20 °C

3: 95 percent / imidazole; 4-(dimethylamino)pyridine / CH₂Cl₂ / 0.5 h / 20 °C

4: 357 mg / OsO₄; NaIO₄ / diethyl ether; H₂O / 18 h / 20 °C

5: 374 mg / LiOH*H₂O / tetrahydrofuran / 14 h / 20 °C

With 1H-imidazole; dmap; lithium hydroxide; sodium periodate; osmium(VIII) oxide; lithium aluminium tetrahydride; Pseudomonas fluorescens lipase AK; In tetrahydrofuran; diethyl ether; dichloromethane; water; benzene;
DOI:10.1021/jo010728d

Reference yield:

: 392655-94-6
1α,2α,3β-3-(prop-1-en-1-yl)-1,2-cyclopropanedimethanol

: 392655-87-7
(2'S,3'R,3S)-ethyl 3-[2'-acetoxymethyl-3'-(tert-butyldiphenylsilanyloxymethyl)cyclopropyl]acrylate

Guidance literature:: Multi-step reaction with 4 steps

1: 97 percent / Pseudomonas fluorescens lipase AK / benzene / 2.5 h / 20 °C

2: 95 percent / imidazole; 4-(dimethylamino)pyridine / CH₂Cl₂ / 0.5 h / 20 °C

3: 357 mg / OsO₄; NaIO₄ / diethyl ether; H₂O / 18 h / 20 °C

4: 374 mg / LiOH*H₂O / tetrahydrofuran / 14 h / 20 °C

With 1H-imidazole; dmap; lithium hydroxide; sodium periodate; osmium(VIII) oxide; Pseudomonas fluorescens lipase AK; In tetrahydrofuran; diethyl ether; dichloromethane; water; benzene;
DOI:10.1021/jo010728d

Reference yield:

: 392655-95-7
(1S,2R,3R)-1-acetoxymethyl-2-hydroxymethyl-3-(1-propenyl)cyclopropane

: 392655-87-7
(2'S,3'R,3S)-ethyl 3-[2'-acetoxymethyl-3'-(tert-butyldiphenylsilanyloxymethyl)cyclopropyl]acrylate

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / imidazole; 4-(dimethylamino)pyridine / CH₂Cl₂ / 0.5 h / 20 °C

2: 357 mg / OsO₄; NaIO₄ / diethyl ether; H₂O / 18 h / 20 °C

3: 374 mg / LiOH*H₂O / tetrahydrofuran / 14 h / 20 °C

With 1H-imidazole; dmap; lithium hydroxide; sodium periodate; osmium(VIII) oxide; In tetrahydrofuran; diethyl ether; dichloromethane; water;
DOI:10.1021/jo010728d