3-Phenyl-1H-indene

Base Information

• Chemical Name: 3-Phenyl-1H-indene
• CAS No.: 1961-97-3
• Molecular Formula: C15H12
• Molecular Weight: 192.26
• NSC Number: 92814
• DSSTox Substance ID: DTXSID00293894
• Nikkaji Number: J582.480J
• Wikidata: Q82032893
• Mol file: 1961-97-3.mol

Synonyms:3-Phenyl-1H-indene;1961-97-3;NSC 92814;1H-Indene, 3-phenyl-;3-phenylindene;NSC92814;3-phenyl-1H-inden;DTXSID00293894;NSC-92814;AKOS004907971;FT-0706260;A813894

Chemical Property of 3-Phenyl-1H-indene

Chemical Property:

• Vapor Pressure: 0.000906mmHg at 25°C
• Refractive Index: 1.637
• Boiling Point: 313.6 °C at 760 mmHg
• Flash Point: 148.6 °C
• Density: 1.104 g/cm³
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 192.093900383
• Heavy Atom Count: 15
• Complexity: 245

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C=C(C2=CC=CC=C21)C3=CC=CC=C3

Technology Process of 3-Phenyl-1H-indene

There total 96 articles about 3-Phenyl-1H-indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-hydroxy 1-phenyl indane (36374-47-7) → 3-phenyl-1H-indene (1961-97-3)

Guidance literature:

iodine; at 25 ℃; for 0.0333333h;

DOI:10.1016/j.tetlet.2006.09.154

Reference yield: 96.0%

3,3-diphenylcyclopropene (22825-21-4) → 3-phenyl-1H-indene (1961-97-3)

Guidance literature:

With silver trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 18h; Solvent; Reagent/catalyst;

DOI:10.1002/asia.201501196

Reference yield: 90.0%

C18H20Si (1000606-89-2) → 3-phenyl-1H-indene (1961-97-3)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; for 2h;

DOI:10.1021/ol702167t

upstream raw materials:

2-phenyl-indan-1-one

phenylmagnesium iodide

inden-1-one

Diethyl carbonate

Downstream raw materials:

1-benzhydrylidene-3-phenyl-indene

3-phenylindene ozonide

2-bromo-1-phenylnaphthalene

dimethyl-[2-(3-phenyl-inden-1-yl)-ethyl]-amine

Refernces

• 1、 Lin, Tao-Yan,Wu, Hai-Hong,Feng, Jian-Jun,Zhang, Junliang. "Transfer of Chirality in the Rhodium-Catalyzed Chemoselective and Regioselective Allylic Alkylation of Hydroxyarenes with Vinyl Aziridines". . p. 2897 - 2900. Retrieved 2017.
• 2、 González, María J.,González, Javier,L?pez, Luís A.,Vicente, Rubén. "Zinc-Catalyzed Alkene Cyclopropanation through Zinc Vinyl Carbenoids Generated from Cyclopropenes". . p. 12139 - 12143. Retrieved 2015.
• 3、 Echavarren, Antonio M.,Mato, Mauro,Montesinos-Magraner, Marc,Sugranyes, Arnau R.. "Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes". supporting information. p. 10760 - 10769. Retrieved 2021/07/28.
• 4、 Borisov, Ilya S.,Busico, Vincenzo,Cipullo, Roberta,Ehm, Christian,Friederichs, Nic,Guzeev, Bogdan A.,Hendriksen, Coen,Mladentsev, Dmitry Y.,Uborsky, Dmitry V.,Vittoria, Antonio,Voskoboynikov, Alexander Z.. "C 1-Symmetric Si-bridged (2-indenyl)(1-indenyl) ansa -metallocenes as efficient ethene/1-hexene copolymerization catalysts". supporting information. p. 3015 - 3025. Retrieved 2020/03/13.