(E)-3-Bromo-2-methyl-acrylic acid methyl ester

Base Information

Chemical Name:(E)-3-Bromo-2-methyl-acrylic acid methyl ester
CAS No.:40053-01-8
Molecular Formula:C5H7BrO2
Molecular Weight:179.013
Hs Code.:2916110090
European Community (EC) Number:858-468-4
Nikkaji Number:J1.943.341B,J260.188E
Mol file:40053-01-8.mol

Synonyms:40053-01-8;(E)-3-Bromo-2-methyl-acrylic acid methyl ester;methyl (E)-3-bromo-2-methylprop-2-enoate;methyl (2E)-3-bromo-2-methylprop-2-enoate;(E)-Methyl 3-bromo-2-methylacrylate;3-BROMO-2-METHYL-ACRYLIC ACID METHYL ESTER;SCHEMBL1821221;3-bromo-2-methylmethyl acrylate;(E)-Methyl3-bromo-2-methylacrylate;MFCD00154501;AKOS006271602;AS-5929;CS-0309186;EN300-1666414

Suppliers and Price of (E)-3-Bromo-2-methyl-acrylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(E)-3-Bromo-2-methyl-acrylicAcidMethylEster
1g
$ 100.00

SynQuest Laboratories
(E)-3-Bromo-2-methylacrylic acid methyl ester
1 g
$ 268.00

SynQuest Laboratories
(E)-3-Bromo-2-methylacrylic acid methyl ester
5 g
$ 988.00

Crysdot
(E)-Methyl3-bromo-2-methylacrylate 97%
5g
$ 1443.00

Crysdot
(E)-Methyl3-bromo-2-methylacrylate 97%
1g
$ 370.00

Biosynth Carbosynth
3-Bromo-2-methyl-methyl acrylate
1 g
$ 100.00

Biosynth Carbosynth
3-Bromo-2-methyl-methyl acrylate
500 mg
$ 60.00

Biosynth Carbosynth
3-Bromo-2-methyl-methyl acrylate
2 g
$ 150.00

Biosynth Carbosynth
3-Bromo-2-methyl-methyl acrylate
5 g
$ 250.00

Biosynth Carbosynth
3-Bromo-2-methyl-methyl acrylate
10 g
$ 400.00

Total 6 raw suppliers

Chemical Property of (E)-3-Bromo-2-methyl-acrylic acid methyl ester

Chemical Property:

Boiling Point:70 - 77 °C (25 mmHg)
PSA：26.30000
LogP:1.45810
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:177.96294
Heavy Atom Count:8
Complexity:118

Purity/Quality:

99% ^*data from raw suppliers

(E)-3-Bromo-2-methyl-acrylicAcidMethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CBr)C(=O)OC
Isomeric SMILES:C/C(=C\Br)/C(=O)OC

Technology Process of (E)-3-Bromo-2-methyl-acrylic acid methyl ester

There total 8 articles about (E)-3-Bromo-2-methyl-acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 40053-01-8
methyl (E)-3-bromo-2-methyl-2-propenoate

Guidance literature:: methacrylic acid methyl ester; With bromine; In tetrachloromethane; at 25 ℃; for 3h;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrachloromethane; at 25 ℃; for 5h;
DOI:10.1016/j.tetlet.2006.07.058

Reference yield: 95.0%

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 40053-01-8,84695-28-3,61442-09-9
methyl 3-bromo-2-methyl-2-propenoate

Guidance literature:: methacrylic acid methyl ester; With bromine; In tetrachloromethane; at 25 ℃; Cooling with ice;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrachloromethane; at 0 - 25 ℃; for 5.25h;
DOI:10.1002/ejoc.201301484

Reference yield: 92.0%

: 547-63-7,133320-07-7,67505-84-4
Methyl isobutyrate

: 40053-01-8
methyl (E)-3-bromo-2-methyl-2-propenoate

Guidance literature:: Methyl isobutyrate; With bromine; In dichloromethane; at 0 - 20 ℃; for 3h; Inert atmosphere;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 ℃; for 5h; Inert atmosphere;
DOI:10.1002/chem.202002297