N-(PHENYLSULFINYL)PHTHALIMIDE 98

Base Information

• Chemical Name: N-(PHENYLSULFINYL)PHTHALIMIDE 98
• CAS No.: 40167-15-5
• Molecular Formula: C14H9NO3S
• Molecular Weight: 271.296
• Hs Code.: 2930909090
• Mol file: 40167-15-5.mol

Synonyms:N-(phenylsulfinyl)phthalimide;2-(Phenylsulfinyl)-1H-isoindole-1,3(2H)-dione;N-(phenylsulphinyl)phthalimide;N-Phenylsulfinyl-phthalimid;1H-Isoindole-1,3(2H)-dione,2-(phenylsulfinyl);N-benzenesulfinyl-phthalimide;

Chemical Property of N-(PHENYLSULFINYL)PHTHALIMIDE 98

Chemical Property:

• Melting Point: 144-148oC(lit.)
• PSA: 73.66000
• LogP: 2.80900

Purity/Quality:

N-(PHENYLSULFINYL)PHTHALIMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(PHENYLSULFINYL)PHTHALIMIDE 98

There total 5 articles about N-(PHENYLSULFINYL)PHTHALIMIDE 98 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

N-phenylthiophthalimide (14204-27-4) → N-(phenylsulphinyl)phthalimide (40167-15-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 0.5h;

Reference yield:

phthalimide (136918-14-4,85-41-6) → N-(phenylsulphinyl)phthalimide (40167-15-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 1) chlorine, 2) N(Et)3 / 1) CH₂Cl₂, 0 deg C, 10 min, 2) CH₂Cl₂, r. t., 1 h

2: 76 percent / 3-chloroperbenzoic acid / CH₂Cl₂ / 0.5 h / 0 °C

With chlorine; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

Reference yield:

thiophenol (108-98-5) → N-(phenylsulphinyl)phthalimide (40167-15-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 1) chlorine, 2) N(Et)3 / 1) CH₂Cl₂, 0 deg C, 10 min, 2) CH₂Cl₂, r. t., 1 h

2: 76 percent / 3-chloroperbenzoic acid / CH₂Cl₂ / 0.5 h / 0 °C

With chlorine; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

upstream raw materials:

N-phenylthiophthalimide

phthalimide

thiophenol

Downstream raw materials:

(-)-menthyl (S)-benzenesulfinate

methyl benzenesulfinate

C₁₅H₁₇NO₃S

trans-(phenylsulfenato)(phthalimido)bis(triphenylphosphane)-platinum(II)

Refernces

• 1、 Kutuk, Halil,Bekdemir, Yunus,Soydas, Yasemin. "Kinetics and mechanisms of the acid-catalyzed hydrolyses of N-(4-substituted-arylsulfinyl)phthalimides". . p. 224 - 228. Retrieved 2007/10/03.