Benzene, 1-[(2,5-dipropoxyphenyl)ethynyl]-4-[(4-ethynyl-2,5-dipropoxyphenyl)ethyn yl]-2,5-dipropoxy-

Base Information

Chemical Name:Benzene, 1-[(2,5-dipropoxyphenyl)ethynyl]-4-[(4-ethynyl-2,5-dipropoxyphenyl)ethyn yl]-2,5-dipropoxy-
CAS No.:406721-49-1
Molecular Formula:C42H50O6
Molecular Weight:650.855
Hs Code.:
Mol file:406721-49-1.mol

Synonyms:

Suppliers and Price of Benzene, 1-[(2,5-dipropoxyphenyl)ethynyl]-4-[(4-ethynyl-2,5-dipropoxyphenyl)ethyn yl]-2,5-dipropoxy-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzene, 1-[(2,5-dipropoxyphenyl)ethynyl]-4-[(4-ethynyl-2,5-dipropoxyphenyl)ethyn yl]-2,5-dipropoxy-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzene, 1-[(2,5-dipropoxyphenyl)ethynyl]-4-[(4-ethynyl-2,5-dipropoxyphenyl)ethyn yl]-2,5-dipropoxy-

There total 13 articles about Benzene, 1-[(2,5-dipropoxyphenyl)ethynyl]-4-[(4-ethynyl-2,5-dipropoxyphenyl)ethyn yl]-2,5-dipropoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 406721-48-0
4-(2,5-dipropoxyphenylethynyl)-1-[2,5-dipropoxy-4-(triisopropylsilylethynyl)phenylethynyl]2,5-dipropoxybenzene

: 406721-49-1
1-(2,5-dipropoxyphenylethynyl)-4-[4-ethynyl-2,5-dopropoxyphenylethynyl]-2,5-dipropoxybenzene

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1002/1099-0690(200112)2001:23<4431::aid-ejoc4431>3.0.co;2-j

Reference yield:

: 3898-41-7
1,4-dipropoxybenzene

: 406721-49-1
1-(2,5-dipropoxyphenylethynyl)-4-[4-ethynyl-2,5-dopropoxyphenylethynyl]-2,5-dipropoxybenzene

Guidance literature:: Multi-step reaction with 7 steps

1: 76 percent / Br₂; NaOAc / acetic acid / 12 h / 20 °C

2: 77 percent / iodine; KIO₃; H₂SO₄ / H₂O; acetic acid; CCl₄ / 5 h / Heating

3: 99 percent / PPh₃; piperidine / PdCl₂(PPh₄)2/CuI / 12 h / 20 °C

4: 99 percent / PPh₃; piperidine / PdCl₂(PPh₄)2/CuI / 20 h

5: 82 percent / nBu₄NF / tetrahydrofuran / 10 h

6: 58 percent / PPh₃; piperidine / PdCl₂(PPh₄)2/CuI / 0.08 h / 20 - 34 °C

7: 90 percent / nBu₄NF / tetrahydrofuran

With piperidine; potassium iodate; sulfuric acid; tetrabutyl ammonium fluoride; bromine; iodine; sodium acetate; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; tetrachloromethane; water; acetic acid; 3: Hagihara-Sonogashira reaction / 4: Hagihara-Sonogashira reaction / 6: Hagihara-Sonogashira reaction;
DOI:10.1002/1099-0690(200112)2001:23<4431::aid-ejoc4431>3.0.co;2-j

Reference yield:

: 123-31-9,8027-02-9
hydroquinone

: 406721-49-1
1-(2,5-dipropoxyphenylethynyl)-4-[4-ethynyl-2,5-dopropoxyphenylethynyl]-2,5-dipropoxybenzene

Guidance literature:: Multi-step reaction with 8 steps

1: 85 percent / KOH / ethanol / 2 h / Heating

2: 76 percent / Br₂; NaOAc / acetic acid / 12 h / 20 °C

3: 77 percent / iodine; KIO₃; H₂SO₄ / H₂O; acetic acid; CCl₄ / 5 h / Heating

4: 99 percent / PPh₃; piperidine / PdCl₂(PPh₄)2/CuI / 12 h / 20 °C

5: 99 percent / PPh₃; piperidine / PdCl₂(PPh₄)2/CuI / 20 h

6: 82 percent / nBu₄NF / tetrahydrofuran / 10 h

7: 58 percent / PPh₃; piperidine / PdCl₂(PPh₄)2/CuI / 0.08 h / 20 - 34 °C

8: 90 percent / nBu₄NF / tetrahydrofuran

With piperidine; potassium iodate; potassium hydroxide; sulfuric acid; tetrabutyl ammonium fluoride; bromine; iodine; sodium acetate; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; tetrachloromethane; ethanol; water; acetic acid; 4: Hagihara-Sonogashira reaction / 5: Hagihara-Sonogashira reaction / 7: Hagihara-Sonogashira reaction;
DOI:10.1002/1099-0690(200112)2001:23<4431::aid-ejoc4431>3.0.co;2-j