1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride

Base Information

• Chemical Name: 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride
• CAS No.: 41168-79-0
• Molecular Formula: C22H14N6O8.2Cl
• Molecular Weight: 561.295
• Hs Code.: 2933399090
• European Community (EC) Number: 677-999-0
• DSSTox Substance ID: DTXSID50557716
• Mol file: 41168-79-0.mol

Synonyms:41168-79-0;1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride;1,1-bis(2,4-dinitrophenyl)-4,4-bipyridinium dichloride;1-(2,4-dinitrophenyl)-4-[1-(2,4-dinitrophenyl)pyridin-1-ium-4-yl]pyridin-1-ium;dichloride;YSZC800;SCHEMBL599994;DTXSID50557716;MFCD00142352;AKOS015833132;B1518;CS-0170542;T70890;A825454;bis(2,4-dinitro-phenyl)-4,4-bipyridinium dichloride;1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridin-1-ium dichloride;1,1'-bis-(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride;1-(2,4-dinitrophenyl)-4-[1-(2,4-dinitrophenyl)-4-pyridin-1-iumyl]pyridin-1-ium dichloride;1-(2,4-dinitrophenyl)-4-[1-(2,4-dinitrophenyl)pyridin-1-ium-4-yl]pyridin-1-ium dichloride

Chemical Property of 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride

Chemical Property:

• PSA: 191.04000
• LogP: -0.35940
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 3
• Exact Mass: 560.0250168
• Heavy Atom Count: 38
• Complexity: 754

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride >97.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C=C1[N+](=O)[O-])[N+](=O)[O-])[N+]2=CC=C(C=C2)C3=CC=[N+](C=C3)C4=C(C=C(C=C4)[N+](=O)[O-])[N+](=O)[O-].[Cl-].[Cl-]

Technology Process of 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride

There total 4 articles about 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium Dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

4,4'-bipyridine (553-26-4) + 1-chloro-2,4-dinitro-benzene (97-00-7) → 1,1′-bis(2,4-dinitrophenyl)-[4,4′-bipyridine]-1,1′-diium chloride (41168-79-0)

Guidance literature:

In acetonitrile; for 72h; Heating;

DOI:10.1021/jo990911v

Reference yield: 74.0%

biphenyl (92-52-4,1594-86-1) + 1-chloro-2,4-dinitro-benzene (97-00-7) → 1,1′-bis(2,4-dinitrophenyl)-[4,4′-bipyridine]-1,1′-diium chloride (41168-79-0)

Guidance literature:

With acetonitrile; In ethanol; for 24h; Reflux;

Reference yield:

4,4'-bipyridine (553-26-4) + 1-chloro-2,4-dinitro-benzene (97-00-7) → 1,1′-bis(2,4-dinitrophenyl)-[4,4′-bipyridine]-1,1′-diium chloride (41168-79-0) + 1-(2,4-dinitrophenyl)-4,4'-bipyridinium chloride (71190-35-7)

Guidance literature:

In ethylene glycol; at 120 ℃; for 6h; Product distribution / selectivity;

upstream raw materials:

4,4'-bipyridine

1-chloro-2,4-dinitro-benzene

biphenyl

4-chlorobenzonitrile

Refernces

• 1、 Leblanc,Mercier,Allain,Dul,Weber,Geoffroy,Bellat,Bezverkhyy. "A robust viologen and Mn-based porous coordination polymer with two types of Lewis acid sites providing high affinity for H2O, CO2 and NH3". . p. 15666 - 15670. Retrieved 2017.
• 2、 Cao, Jiajun,Huang, Feihe,Li, Qi,Liu, Yang,Shangguan, Liqing,Wang, Feng,Wang, Zeju,Wu, Yitao,Zhu, Huangtianzhi. "Chemoresponsive Supramolecular Polypseudorotaxanes with Infinite Switching Capability". . p. 19997 - 20002. Retrieved 2021.
• 3、 Zhang, Beilin,Dong, Yunhong,Li, Jie,Yu, Yang,Li, Chenyang,Cao, Liping. "Pseudo[n,m]rotaxanes of Cucurbit[7/8]uril and Viologen-Naphthalene Derivative: A Precise Definition of Rotaxane". . p. 269 - 275. Retrieved 2019.
• 4、 Liu, Jian-Jun,Guan, Ying-Fang,Lin, Mei-Jin,Huang, Chang-Cang,Dai, Wen-Xin. "Luminescent coordination polymer with conjugated lewis acid sites for the detection of organic amines". . p. 5040 - 5046. Retrieved 2015.
• 5、 Wang, Shanshan,Li, Shuning,Xiong, Junyu,Lin, Zhengguo,Wei, Wei,Xu, Yanqing. "Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer". . p. 7399 - 7402. Retrieved 2020.
• 6、 Zhao, Jing,Qu, Xianglong,Yan, Bing. "Lanthanide coordination polymers of viologen carboxylic acid: Crystal structures and luminescence response tuning". . . Retrieved 2020.
• 7、 Leroux, Maxime,Weber, Guy,Bellat, Jean-Pierre,Bezverkhyy, Igor,Mercier, Nicolas. "Supramolecular Open-Framework of a Bipyridinium-Carboxylate Based Copper Complex with High and Reversible Water Uptake". . p. 1439 - 1444. Retrieved 2016.
• 8、 Yu, Yang,Li, Yawen,Wang, Xiaoqing,Nian, Hao,Wang, Le,Li, Jie,Zhao, Yanxia,Yang, Xiran,Liu, Simin,Cao, Liping. "Cucurbit[10]uril-Based [2]Rotaxane: Preparation and Supramolecular Assembly-Induced Fluorescence Enhancement". . p. 5590 - 5596. Retrieved 2017.
• 9、 Liu, Lu,Qu, Wei-Dong,Dong, Kai-Xun,Qi, Ye,Gong, Wei-Tao,Ning, Gui-Ling,Cui, Jing-Nan. "An anthracene extended viologen-incorporated ionic porous organic polymer for efficient aerobic photocatalysis and antibacterial activity". supporting information. p. 3339 - 3342. Retrieved 2021/04/07.