9,10-dihydro-9,10-epidioxyanthracene

Base Information

• Chemical Name: 9,10-dihydro-9,10-epidioxyanthracene
• CAS No.: 4741-24-6
• Molecular Formula: C14H10 O2
• Molecular Weight: 210.232
• Mol file: 4741-24-6.mol

Synonyms:Anthracene,photooxide (6CI,7CI); Anthracene 9,10-endoperoxide; Anthracene, peroxide;Anthracene-9,10-epiperoxide

Chemical Property of 9,10-dihydro-9,10-epidioxyanthracene

Chemical Property:

• Vapor Pressure: 0.000655mmHg at 25°C
• Boiling Point: 318.9°Cat760mmHg
• Flash Point: 136.3°C
• Density: 1.276g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9,10-dihydro-9,10-epidioxyanthracene

There total 4 articles about 9,10-dihydro-9,10-epidioxyanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

p-cresol (106-44-5) + anthracene (120-12-7) → 9,10-epidioxy-9,10-dihydroanthracene (4741-24-6) + 4-hydroperoxy-4-methyl-2,5-cyclohexadien-1-one (57749-82-3)

Guidance literature:

With 2,6-diiodo-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indacene; oxygen; In chloroform-d1; at 20 ℃; for 2h; Schlenk technique; Irradiation;

DOI:10.1055/s-0039-1690796

Reference yield:

anthracene (120-12-7) → 9,10-epidioxy-9,10-dihydroanthracene (4741-24-6) + oxanthrone (549-99-5) + 9,10-phenanthrenequinone (84-65-1)

Guidance literature:

With oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate; In [D₃]acetonitrile; at 20 ℃; Further Variations:; time; Product distribution; photoirradiation;

DOI:10.1021/ja048353b

Reference yield:

anthracene (120-12-7) → 9,10-epidioxy-9,10-dihydroanthracene (4741-24-6) + 9,10-phenanthrenequinone (84-65-1)

Guidance literature:

With oxygen; In water; Irradiation; 10percent conversion of anthracene;

DOI:10.1016/S0040-4039(00)93543-3

upstream raw materials:

anthracene

p-cresol

Downstream raw materials:

syn 4a,10:9,9a-diepoxy-4a,9,9a,10-tetrahydroanthracene

4b,10a-Dihydro-5,10-dioxa-benzo[b]biphenylene

9,10-phenanthrenequinone

6,11-epoxy-6,11-dihydrodibenzooxepine

Refernces

• 1、 Yamashita, Ken-ichi,Sugiura, Ken-ichi. "Photochemical reaction of anthracene with dioxygen catalyzed by platinum(II) porphyrin". . . Retrieved 2019.
• 2、 Coeffard, Vincent,Fischer, Jér?me,Nun, Pierrick,Serier-Brault, Hélène. "Substrate-Selectivity in Catalytic Photooxygenation Processes Using a Quinine-BODIPY System". supporting information. p. 463 - 468. Retrieved 2020/03/13.
• 3、 Kotani, Hiroaki,Ohkubo, Kei,Fukuzumi, Shunichi. "Photocatalytic oxygenation of anthracenes and olefins with dioxygen via selective radical coupling using 9-mesityl-10-methylacridinium ion as an effective electron-transfer photocatalyst". . p. 15999 - 16006. Retrieved 2007/10/03.