p-Formylphenyl methacrylate

Base Information

• Chemical Name: p-Formylphenyl methacrylate
• CAS No.: 36195-33-2
• Molecular Formula: C11H10 O3
• Molecular Weight: 190.199
• Hs Code.: 2916140000
• European Community (EC) Number: 252-906-2
• UNII: 98MGL3QL2K
• DSSTox Substance ID: DTXSID20189760
• Nikkaji Number: J319.579A
• Wikidata: Q83061968
• Mol file: 36195-33-2.mol

Synonyms:p-Formylphenyl methacrylate;4-formylphenyl methacrylate;36195-33-2;(4-formylphenyl) 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, 4-formylphenyl ester;98MGL3QL2K;EINECS 252-906-2;4-formylphenyl 2-methylprop-2-enoate;UNII-98MGL3QL2K;SCHEMBL7738348;DTXSID20189760;Methacrylic acid 4-formylphenyl ester

Chemical Property of p-Formylphenyl methacrylate

Chemical Property:

• Vapor Pressure: 0.000228mmHg at 25°C
• Boiling Point: 325.6°Cat760mmHg
• Flash Point: 144.3°C
• PSA: 43.37000
• Density: 1.141g/cm³
• LogP: 1.98060
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 190.062994177
• Heavy Atom Count: 14
• Complexity: 237

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1=CC=C(C=C1)C=O

Technology Process of p-Formylphenyl methacrylate

There total 3 articles about p-Formylphenyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

4-hydroxy-benzaldehyde (123-08-0,65581-83-1) + Methacryloyl chloride (920-46-7,26937-45-1) → 4-Formylphenyl methacrylate (36195-33-2)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 10h;

DOI:10.1021/ol0705191

Reference yield: 89.2%

methacryloyl anhydride (760-93-0) + 4-hydroxy-benzaldehyde (123-08-0,65581-83-1) → 4-Formylphenyl methacrylate (36195-33-2)

Guidance literature:

With dmap; In dichloromethane; at 40 ℃; for 14h; Inert atmosphere;

DOI:10.4067/S0717-97072017000200025

Reference yield:

→ 4-Formylphenyl methacrylate (36195-33-2)

Guidance literature:

/BRN= 2044721/;

DOI:10.1002/macp.1959.020310103

upstream raw materials:

4-hydroxy-benzaldehyde

Methacryloyl chloride

methacryloyl anhydride

Refernces

• 1、 Eing, Matthias,Tuten, Bryan T.,Blinco, James P.,Barner-Kowollik, Christopher. "Visible Light Activation of Spin-Silenced Fluorescence". . p. 12246 - 12249. Retrieved 2018.
• 2、 Gayvoronsky, Volodymyr Ya.,Kolendo, Oleksiy Yu.,Kulai, Ihor V.,Multian, Volodymyr V.,Ovdenko, Valeriia M.,Uklein, Andrii V.. "Novel efficient nonlinear optical azo- And azomethine polymers containing an antipyrine fragment: Synthesis and characterization". . p. 9032 - 9045. Retrieved 2020.