Triethylorthoacrylate

Base Information

• Chemical Name: Triethylorthoacrylate
• CAS No.: 42216-96-6
• Molecular Formula: C9H18O3
• Molecular Weight: 174.24
• Mol file: 42216-96-6.mol

Synonyms:1-propene,3,3,3-triethoxy;3,3,3-Triethoxy-1-propene;1,1,1-triethoxy-2-propene;triethyl orthoacrylate;orthoacrylic acid triethyl ester;

Chemical Property of Triethylorthoacrylate

Chemical Property:

• PSA: 27.69000
• LogP: 1.93570

Purity/Quality:

98%Min ^*data from raw suppliers

3,3,3-TRIETHOXYPROP-1-ENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Triethylorthoacrylate

There total 2 articles about Triethylorthoacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2-bromo-1,1,1-triethoxypropane (42216-95-5) → triethyl orthoacrylate (42216-96-6)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; Ambient temperature;

DOI:10.1016/0040-4039(88)85175-X

Reference yield: 58.0%

Triethyl orthopropionate (115-80-0) → triethyl orthoacrylate (42216-96-6)

Guidance literature:

Triethyl orthopropionate; With pyridine; bromine; at 0 ℃; for 2h; Inert atmosphere;

With potassium tert-butylate; In dimethyl sulfoxide; at 20 ℃; for 6h; Inert atmosphere;

DOI:10.1002/ejoc.201800205

Reference yield: 99.0%

triethyl orthoacrylate (42216-96-6) + 4-(4-methoxyphenyl)naphthalen-1-ol → C24H26O4

Guidance literature:

With Trimethylacetic acid; In toluene; for 24h; Reflux;

DOI:10.1246/cl.141130

upstream raw materials:

2-bromo-1,1,1-triethoxypropane

Triethyl orthopropionate

Downstream raw materials:

ethyl isocaproate

ethyl 4,4-dimethylpentanoate

ethyl heptanoate

ethyl 4-benzoylbutanoate

Refernces

• 1、 Karanfil, Abdullah,Eskici, Mustafa. "Practical synthesis of functionalized terminal alkynes, 3,3,3-triethoxypropyne and ketal protected prop-2-ynones". supporting information. p. 2342 - 2351. Retrieved 2017/12/12.
• 2、 Gassman, Paul G.,Chavan, Subhash P.. "The Low-Temperature, Ionic Diels-Alder Addition of Vinyl Ortho Esters to 1,3-Dienes". . p. 2392 - 2394. Retrieved 2007/10/02.