2,2,6,6-Tetramethyl-4-(4'-toluenesulfonate)piperidinooxyl

Base Information

Chemical Name:2,2,6,6-Tetramethyl-4-(4'-toluenesulfonate)piperidinooxyl
CAS No.:42495-21-6
Molecular Formula:C16H24NO4S
Molecular Weight:326.437
Hs Code.:
Mol file:42495-21-6.mol

Synonyms:(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl) 4-methylbenzenesulfonate;

Suppliers and Price of 2,2,6,6-Tetramethyl-4-(4'-toluenesulfonate)piperidinooxyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,2,6,6-Tetramethyl-4-(4''-toluenesulfonate)piperidinooxyl
500 mg
$ 140.00

American Custom Chemicals Corporation
2,2,6,6-TETRAMETHYL-4-(4'-TOLUENESULFONATE)PIPERIDINOOXYL 95.00%
5MG
$ 502.17

Total 4 raw suppliers

Chemical Property of 2,2,6,6-Tetramethyl-4-(4'-toluenesulfonate)piperidinooxyl

Chemical Property:

Vapor Pressure:6.09E-09mmHg at 25°C
Boiling Point:451.6oC at 760 mmHg
Flash Point:226.9oC
PSA：75.22000
Density:1.23g/cm3
LogP:4.12980
Storage Temp.:Refrigerator

Purity/Quality:

95% ^*data from raw suppliers

2,2,6,6-Tetramethyl-4-(4''-toluenesulfonate)piperidinooxyl ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses An intermediate in the preparation of Piperidine-1-oxyl derivatives.

Technology Process of 2,2,6,6-Tetramethyl-4-(4'-toluenesulfonate)piperidinooxyl

There total 2 articles about 2,2,6,6-Tetramethyl-4-(4'-toluenesulfonate)piperidinooxyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 45985-24-8,2226-96-2
TEMPOL

: 98-59-9
p-toluenesulfonyl chloride

: 42495-21-6
4-tosyloxy-2,2,6,6-tetramethylpiperidine N-oxyl

Guidance literature:: With pyridine; at 20 ℃;
DOI:10.1002/pola.29400

Reference yield:

: 42495-21-6
4-tosyloxy-2,2,6,6-tetramethylpiperidine N-oxyl

Guidance literature:: Aus 4-Hydroxy-2,2,6,6-tetramethyl-piperidin-1-oxid u. p-Toluolsulfonylchlorid in Py.+Bzl.;

Reference yield: 83.0%

: 42495-21-6
4-tosyloxy-2,2,6,6-tetramethylpiperidine N-oxyl

: 5670-65-5,15795-70-7,15241-24-4
(E)-1-nitro-2-phenyl-1-propene

: (E)-2,2,6,6-tetramethyl-1-((3-oxo-2-phenylprop-1-en-1-yl)oxy)piperidin-4-yl 4-methylbenzenesulfonate

Guidance literature:: With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide; In acetonitrile; at 80 ℃; for 2h;
DOI:10.1021/acs.orglett.0c04106