Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester

Base Information

Chemical Name:Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester
CAS No.:27872-59-9
Molecular Formula:C₉H₁₄O₃
Molecular Weight:170.208
Hs Code.:
NSC Number:166631
Nikkaji Number:J1.251.406I,J1.419.177A
Mol file:27872-59-9.mol

Synonyms:NSC166631;4-Methyl-6-acetoxy-4-hexenal;SCHEMBL2560933;e-6-acetoxy-4-methyl-4-hexenal;RGAIVGKJOJFCTG-VMPITWQZSA-N;27872-59-9;(4E)-6-Acetoxy-4-methyl-4-hexenal;AKOS024332050;NSC-166631;(2E)-3-Methyl-6-oxo-2-hexenyl acetate #;Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester;ACETIC ACID 3-METHYL-6-OXO-HEX-2-ENYL ESTER

Suppliers and Price of Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester

Chemical Property:

Vapor Pressure:0.0182mmHg at 25°C
Boiling Point:253.5°C at 760 mmHg
Flash Point:105.8°C
Density:0.993g/cm³
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:170.094294304
Heavy Atom Count:12
Complexity:182

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CCOC(=O)C)CCC=O
Isomeric SMILES:C/C(=C\COC(=O)C)/CCC=O

Technology Process of Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester

There total 1 articles about Acetic acid, 3-methyl-6-oxo-hex-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 27872-59-9,35334-60-2,37905-00-3
3-methyl-6-oxohex-2-enyl acetate

Guidance literature:: Geranylacetat, O3;

Reference yield:

: 27872-59-9,35334-60-2,37905-00-3
3-methyl-6-oxohex-2-enyl acetate

: 145588-95-0,334968-78-4
N-propanoyl-(S)-4-benzyl-1,3-oxazolidine-2-thione

: (4S)-4-benzyl-3-[(2R,3S)-8-acetoxy-2,6-dimethyl-3-hydroxy-1-oxo-oct-6-enyl]-1,3-oxazolidine-2-thione

Guidance literature:: N-propanoyl-(S)-4-benzyl-1,3-oxazolidine-2-thione; With titanium tetrachloride; In dichloromethane; at 0 ℃; for 0.0833333h; Inert atmosphere;

With (-)-sparteine; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

3-methyl-6-oxohex-2-enyl acetate; In dichloromethane; at -78 ℃; for 8h; Inert atmosphere;
DOI:10.1039/c1ob05448a

Reference yield:

: 27872-59-9,35334-60-2,37905-00-3
3-methyl-6-oxohex-2-enyl acetate

: 40772-85-8
((2E,6E)-7-Methoxycarbonyl-3-methyl-octa-2,6-dienyl)-triphenyl-phosphonium; bromide

Guidance literature:: Multi-step reaction with 3 steps

1: benzene / Heating

2: KOH / methanol

3: CH₂Cl₂ / Heating

With potassium hydroxide; In methanol; dichloromethane; benzene;