(4-Bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane

Base Information

Chemical Name:(4-Bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane
CAS No.:431879-38-8
Molecular Formula:C23H25BrO2Si
Molecular Weight:441.44
Hs Code.:
DSSTox Substance ID:DTXSID40446266
Wikidata:Q82264878
Mol file:431879-38-8.mol

Synonyms:431879-38-8;(4-bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane;Silane, (4-bromo-2-methoxyphenoxy)(1,1-dimethylethyl)diphenyl-;SCHEMBL5334814;DTXSID40446266;TUTDWHJFVBJUJV-UHFFFAOYSA-N

Suppliers and Price of (4-Bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (4-Bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:440.08072
Heavy Atom Count:27
Complexity:434

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OC3=C(C=C(C=C3)Br)OC

Technology Process of (4-Bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane

There total 2 articles about (4-Bromo-2-methoxy-phenoxy)-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7368-78-7
4-bromoguaiacol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 431879-38-8
4-(tert-butyldiphenylsilanoxy)-3-methoxybromobenzene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 52h;
DOI:10.1021/jo016220s

Reference yield:

: 90-05-1
2-methoxy-phenol

: 431879-38-8
4-(tert-butyldiphenylsilanoxy)-3-methoxybromobenzene

Guidance literature:: Multi-step reaction with 2 steps

1: bromine / CS₂ / 18 h / 0 °C

2: imidazole / dimethylformamide / 52 h

With 1H-imidazole; bromine; In carbon disulfide; N,N-dimethyl-formamide;
DOI:10.1021/jo016220s

Reference yield:

: 5419-55-6
Triisopropyl borate

: 431879-38-8
4-(tert-butyldiphenylsilanoxy)-3-methoxybromobenzene

: 482309-54-6
4-(tert-buthyl-diphenyl-silanyloxy)-3-methoxy-phenyl-boronic acid

Guidance literature:: Triisopropyl borate; 4-(tert-butyldiphenylsilanoxy)-3-methoxybromobenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

With hydrogenchloride; In tetrahydrofuran; water; at 0 - 20 ℃; for 0.5h;