1b,2,5,5a,6,6a-Hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene

Base Information

Chemical Name:1b,2,5,5a,6,6a-Hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene
CAS No.:4387-45-5
Molecular Formula:C₁₀H₁₂O
Molecular Weight:148.205
Hs Code.:
NSC Number:96562
DSSTox Substance ID:DTXSID80294420
Nikkaji Number:J195.741D
Mol file:4387-45-5.mol

Synonyms:4387-45-5;1b,2,5,5a,6,6a-hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene;NSC96562;SCHEMBL522403;DTXSID80294420;NSC-96562;4,5-epoxytricyclo[5.2.1.02,6]dec-8-ene;epoxy-2,3,3a,4,7,7a-hexa-hydro-4,7-methanoindene;Endo-4-oxatetracyclo[6.2.1.0(2,7).0(3,5)]undec-9-ene;4-Oxatetracyclo[6.2.1.0(2,7).0(3,5)]undec-9-ene (endo)-;52154-83-3

Suppliers and Price of 1b,2,5,5a,6,6a-Hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1b,2,5,5a,6,6a-Hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene

Chemical Property:

PSA：12.53000
LogP:1.59580
XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:148.088815002
Heavy Atom Count:11
Complexity:245

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C2C=CC1C3C2CC4C3O4

Technology Process of 1b,2,5,5a,6,6a-Hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene

There total 9 articles about 1b,2,5,5a,6,6a-Hexahydro-1ah-2,5-methanoindeno[1,2-b]oxirene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.6%

: 1755-01-7,25038-78-2
endo-Dicyclopentadien

: 4387-46-6,52154-84-4,52882-08-3
endo-9-Oxatetracyclo<5.3.1.0^2.6.0^8.10>undec-3-ene

: 4387-45-5,52154-83-3,52882-09-4,91109-11-4
C₁₀H₁₂O

Guidance literature:: With tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI); In chlorobenzene; at 90 ℃;

Reference yield: 50.0%

: 77-73-6,933-60-8,1755-01-7,25038-78-2
bi(cyclopentadiene)

: 81-21-0,4168-48-3,29987-76-6
dicyclopentadiene dioxide

: 4387-46-6,52154-84-4,52882-08-3
Norbonenoxid

: 52154-83-3,91109-11-4,4387-45-5,52882-09-4
1,2-epoxy-3a,4,7,7a-tetrahydro-4,7-methano-indane

Guidance literature:: With sodium perborate; acetic anhydride; In dichloromethane; Title compound not separated from byproducts; Ambient temperature; 16-24 h;
DOI:10.1016/0040-4039(88)85059-7

Reference yield: 38.0%

: 77-73-6,933-60-8,1755-01-7,25038-78-2
bi(cyclopentadiene)

: 4387-46-6,52154-84-4,52882-08-3
Norbonenoxid

: 52154-83-3,91109-11-4,4387-45-5,52882-09-4
1,2-epoxy-3a,4,7,7a-tetrahydro-4,7-methano-indane

Guidance literature:: With [(C₁₈H₃₇)₂(CH₃)₂N]₃[SiO₄H(WO₅)₃]; dihydrogen peroxide; In ethyl acetate; at 59.84 ℃; for 2h; Green chemistry;
DOI:10.1039/c4ra04036h