methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside

Base Information

Chemical Name:methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside
CAS No.:4969-34-0
Molecular Formula:C13H19NO10
Molecular Weight:349.2907
Hs Code.:
NSC Number:170246
DSSTox Substance ID:DTXSID80305328

Synonyms:4969-34-0;NSC170246;methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside;DTXSID80305328;NSC-170246

Suppliers and Price of methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside

Chemical Property:

Vapor Pressure:1.8E-07mmHg at 25°C
Boiling Point:426.2°C at 760 mmHg
Flash Point:166°C
Density:1.33g/cm³
XLogP3:-0.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:8
Exact Mass:349.10089580
Heavy Atom Count:24
Complexity:502

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OC1C(OC(C(C1OC(=O)C)OC(=O)C)OC)C[N+](=O)[O-]

Technology Process of methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside

There total 4 articles about methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitrohexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 6304-96-7
methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-glucopyranoside

: 4969-34-0
methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitro-α-D-glucopyranoside

Guidance literature:: With sodium nitrite; recorcinol; In N,N-dimethyl-formamide; at 20 ℃; for 72h;

Reference yield:

: 97-30-3
methyl-alpha-D-glucopyranoside

: 4969-34-0
methyl 2,3,4-tri-O-acetyl-6-deoxy-6-nitro-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: iodine; triphenylphosphine; 1H-imidazole / N,N-dimethyl-formamide / 2 h / 70 °C

2: pyridine / 20 h / 20 °C / Cooling with ice

3: sodium nitrite; recorcinol / N,N-dimethyl-formamide / 72 h / 20 °C

With pyridine; 1H-imidazole; iodine; triphenylphosphine; sodium nitrite; recorcinol; In N,N-dimethyl-formamide;