(2R,3R)-2,3-dihydroxybutane-1,4-diyl dinitrate

Base Information

• Chemical Name: (2R,3R)-2,3-dihydroxybutane-1,4-diyl dinitrate
• CAS No.: 28368-55-0
• Molecular Formula: C₄H₈N₂O₈
• Molecular Weight: 212.116
• Mol file: 28368-55-0.mol

Synonyms:1,2,3,4-Butanetetrol,1,4-dinitrate, (R*,R*)-(?à)-; Erythritol, 1,4-dinitrate, DL- (8CI)

Chemical Property of (2R,3R)-2,3-dihydroxybutane-1,4-diyl dinitrate

Chemical Property:

• Vapor Pressure: 0.172mmHg at 25°C
• Boiling Point: 187.7°C at 760 mmHg
• Flash Point: 67.3°C
• Density: 1.649g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2R,3R)-2,3-dihydroxybutane-1,4-diyl dinitrate

There total 5 articles about (2R,3R)-2,3-dihydroxybutane-1,4-diyl dinitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

1,2:3,4-Diepoxybutane (564-00-1,1464-53-5,30031-64-2,30419-67-1,34897-03-5,298-18-0) → erythtritol 1,4-dinitrate (28368-55-0)

Guidance literature:

With tetranitromethane; triethylamine; In 1,4-dioxane; at 20 ℃; for 168h;

DOI:10.1016/j.tetlet.2008.04.050

Reference yield:

(2R,3S)-4-Nitrooxy-butane-1,2,3-triol (138779-56-3) → 1,4-dinitrate meso-erythritol (20113-39-7,28368-55-0)

Guidance literature:

With nitric acid; In water; at 20 ℃; Equilibrium constant;

DOI:10.1007/BF00963488

Reference yield:

(2R,3S)-1,3,4-Tris-nitrooxy-butan-2-ol (138779-57-4) → 1,4-dinitrate meso-erythritol (20113-39-7,28368-55-0)

Guidance literature:

With water; at 20 ℃; Equilibrium constant;

DOI:10.1007/BF00963488

upstream raw materials:

(2R,3S)-4-Nitrooxy-butane-1,2,3-triol

(2R,3S)-1,3,4-Tris-nitrooxy-butan-2-ol

1,4-bis-nitrooxy-but-2t-ene

1,2:3,4-Diepoxybutane

Refernces

• 1、 Volkova, Yuliya A.,Ivanova, Olga A.,Budynina, Ekaterina M.,Averina, Elena B.,Kuznetsova, Tamara S.,Zefirov, Nikolai S.. "Tetranitromethane as an efficient reagent for the conversion of epoxides into β-hydroxy nitrates". . p. 3935 - 3938. Retrieved 2008/09/21.