(2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide

Base Information

Chemical Name:(2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide
CAS No.:7505-44-4
Molecular Formula:C15H12N6O5
Molecular Weight:356.297
Hs Code.:
NSC Number:48616
DSSTox Substance ID:DTXSID10425922
Wikidata:Q82238869

Synonyms:7505-44-4;DTXSID10425922;NSC48616;NSC-48616;(2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide

Suppliers and Price of (2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of (2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:4
Exact Mass:356.08691750
Heavy Atom Count:26
Complexity:522

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC(=C1)[N+](=O)[O-])C=NNC(=O)NN=CC2=CC(=CC=C2)[N+](=O)[O-]
Isomeric SMILES:C1=CC(=CC(=C1)[N+](=O)[O-])/C=N/NC(=O)N/N=C\C2=CC(=CC=C2)[N+](=O)[O-]

Technology Process of (2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide

There total 2 articles about (2E)-N'-[(Z)-(3-Nitrophenyl)methylidene]-2-[(3-nitrophenyl)methylidene]hydrazine-1-carbohydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 3748-99-0
N'-(3-nitrobenzylidene)-4-methylbenzenesulfonohydrazide

: 584-08-7
potassium carbonate

: 7505-44-4
(m-NO₂C₆H₄)CHNNHCONHNCH(m-NO₂C₆H₄)

Guidance literature:: With phosphonic acid diethyl ester; In dimethyl sulfoxide; at 60 ℃; for 10h;
DOI:10.1021/ol500732c

Reference yield:

: 99-61-6
3-nitro-benzaldehyde

: 7505-44-4
(m-NO₂C₆H₄)CHNNHCONHNCH(m-NO₂C₆H₄)

Guidance literature:: Multi-step reaction with 2 steps

1: methanol / 1 h / Reflux

2: phosphonic acid diethyl ester / dimethyl sulfoxide / 10 h / 60 °C

With phosphonic acid diethyl ester; In methanol; dimethyl sulfoxide;
DOI:10.1021/ol500732c

Reference yield: 65.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 7505-44-4
(m-NO₂C₆H₄)CHNNHCONHNCH(m-NO₂C₆H₄)

: mono(cyclopentadienyl)((m-NO₂C₆H₄)CHNNHCONHNCH(m-NO₂C₆H₄))titanium(IV) trichloride

Guidance literature:: In dichloromethane; mono(cyclopentadienyl)titanium(IV) trichloride was dissolved in anhydrous CH2Cl2, Schiff base was added, the mixt. was refluxed for 30-50 h; ptt. was filtered, washed with hexane, dried under vac., crystn. from CH3Cl; elem. anal.;