Dihydrochelirubine

Base Information

Chemical Name:Dihydrochelirubine
CAS No.:28342-26-9
Molecular Formula:C₂₁H₁₇NO₅
Molecular Weight:363.37
Hs Code.:
DSSTox Substance ID:DTXSID00331503
Nikkaji Number:J452.140D
Wikidata:Q3707626
Metabolomics Workbench ID:51041
ChEMBL ID:CHEMBL518879
Mol file:28342-26-9.mol

Synonyms:Dihydrochelirubine;28342-26-9;CHEBI:17789;13,14-Dihydro-5-methoxy-13-methyl-[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine;15-methoxy-24-methyl-5,7,18,20-tetraoxa-24-azahexacyclo[11.11.0.02,10.04,8.014,22.017,21]tetracosa-1(13),2,4(8),9,11,14,16,21-octaene;5-methoxy-13-methyl-13,14-dihydro-2H,10H-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridine;Dihydrobocconine;C05194;SCHEMBL891981;CHEMBL518879;DTXSID00331503;HY-N10366;CS-0434734;Q3707626;13, 14-dihydro-5-methoxy-13-methyl-[1, 3]benzodioxolo[5, 6-c]-1, 3-dioxolo[4, 5-i]phenanthridine

Suppliers and Price of Dihydrochelirubine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 0 raw suppliers

Chemical Property of Dihydrochelirubine

Chemical Property:

Vapor Pressure:6.01E-14mmHg at 25°C
Boiling Point:591.1°C at 760 mmHg
Flash Point:181.1°C
PSA：49.39000
Density:1.41g/cm³
LogP:3.98760
XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:363.11067264
Heavy Atom Count:27
Complexity:575

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN1CC2=C3C(=CC(=C2C4=C1C5=CC6=C(C=C5C=C4)OCO6)OC)OCO3

Technology Process of Dihydrochelirubine

There total 10 articles about Dihydrochelirubine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 66209-37-8
2-(2-methoxy-4,5-methylenedioxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene

: 28342-26-9
dihydrochelirubine

: 2,3-(1-hydroxy-8-oxabicyclo[3.2.1]octeno)-1-methyl-7,8-methylenedioxybenz[g]indole

Guidance literature:: 2-(2-methoxy-4,5-methylenedioxyphenyl)-6,7-methylenedioxy-1-(N-methylformamido)naphthalene; With trichlorophosphate; at 70 ℃; for 9h;

With sodium tetrahydroborate; In methanol; at 20 ℃; for 2h; Further stages.;
DOI:10.1021/jo0012849

Reference yield:

: 28342-31-6
6-Ethoxy-5,6-dihydrosanguinarine

: 28342-26-9
dihydrochelirubine

Guidance literature:: Multi-step reaction with 4 steps

2: 28 mg / H₂ / Raney Ni / methanol / 4 h / Ambient temperature

3: 1.) HCl, isopentyl nitrite / 1.) AcOH, -5 deg C, 20 min, 2.) RT, 24 h

4: 1.5 mg / NaBH₄ / methanol / 0.25 h / Ambient temperature

With hydrogenchloride; sodium tetrahydroborate; hydrogen; isopentyl nitrite; nickel; In methanol;
DOI:10.1002/jhet.5570280806

Reference yield:

: 139332-32-4
10-nitromethoxysanguinarine

: 28342-26-9
dihydrochelirubine

Guidance literature:: Multi-step reaction with 3 steps

1: 28 mg / H₂ / Raney Ni / methanol / 4 h / Ambient temperature

2: 1.) HCl, isopentyl nitrite / 1.) AcOH, -5 deg C, 20 min, 2.) RT, 24 h

3: 1.5 mg / NaBH₄ / methanol / 0.25 h / Ambient temperature

With hydrogenchloride; sodium tetrahydroborate; hydrogen; isopentyl nitrite; nickel; In methanol;
DOI:10.1002/jhet.5570280806